83
Bi
Bismuth
Atomic Mass 208.98040
Electron Configuration [Xe]6s24f145d106p3
Oxidation States +5, +3
Year Discovered 1753

Identifiers

Element Name Bismuth
Element Symbol Bi
InChI InChI=1S/Bi
InChIKey JCXGWMGPZLAOME-UHFFFAOYSA-N

Properties

Atomic Weight

208.980 40(1)

208.98040

209.0

208.98040(1)

Electron Configuration

[Xe]6s24f145d106p3

Atomic Radius

Van der Waals Atomic Radius : 207 pm (Van der Waals)

Empirical Atomic Radius : 160pm (Empirical)

Covalent Atomic Radius : 148(4) pm (Covalent)

Oxidation States

+5, +3

5, 4, 3, 2, 1, -1, -2, -3

Ground Level

43/2

Ionization Energy

7.289 eV

7.285516 ± 0.000006 eV

Electronegativity

Pauling Scale Electronegativity : 2.02(Pauling Scale)

Allen Scale Electronegativity : 2.01(Allen Scale)

Electron Affinity

0.946eV

0.95eV

Atomic Spectra

Lines Holdings

Levels Holdings

Physical Description

Solid

Element Classification

Metal

Element Period Number

6

Element Group Number

15 - Pnictogen

Density

9.807 grams per cubic centimeter

Melting Point

544.55 K (271.40°C or 520.52°F)

271.5°C

Boiling Point

1837 K (1564°C or 2847°F)

1564°C

Estimated Crustal Abundance

8.5×10-3 milligrams per kilogram

Estimated Oceanic Abundance

2×10-5 milligrams per liter

History

The name derives from the German weisse masse for "white mass" from the colour of its oxides. The ancients did not distinguish bismuth from lead. The French chemist Claude-Francois Geoffroy showed that bismuth was distinct from lead in 1753.

Bismuth, which has been known since ancient times, was often confused with lead and tin. Bismuth was first shown to be a distinct element in 1753 by Claude Geoffroy the Younger. Bismuth does occur free in nature and in such minerals as bismuthinite (Bi2S3) and bismite (Bi2O3). The largest deposits of bismuth are found in Bolivia, although bismuth is usually obtained as a by-product of mining and refining lead, copper, tin, silver and gold.

From the German Weisse Masse, meaning white mass; later Wisuth and Bisemutum. In early times bismuth was confused with tin and lead. Claude Geoffroy the Younger showed it to be distinct from lead in 1753.

Historical Atomic Weights

Year Atomic Weight (uncertainty) [u] Reference
2005 208.980 40(1) https://doi.org/10.1351/pac200678112051
1995 208.980 38(2) https://doi.org/10.1351/pac199668122339
1985 208.980 37(3) https://doi.org/10.1351/pac198658121677
1971 208.9804(1) https://doi.org/10.1351/pac197230030637
1969 208.9806(1) https://doi.org/10.1351/pac197021010091
1961 208.980 https://doi.org/10.1021/ja00881a001
1925 209.00 https://doi.org/10.1039/CT9252700913
1922 209.0 https://doi.org/10.1021/ja01441a001
1907 208.0 https://doi.org/10.1021/ja01956a001
1902 208.5 https://doi.org/10.1007/BF01370337

Historical Isotopic Abundances

Year Isotope Abundance (uncertainty) Reference
1975, 209Bi, 1, doi:10.1351/pac197647010075

Description

It is a white, crystalline, brittle metal with a pinkish tinge. It occurs in a native state. Bismuth is the most diamagnetic of all metals, and the thermal conductivity is lower than any metal, except mercury. It has a high electrical resistance, and has the highest Hall effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field).

Users

Pure bismuth is a white, brittle metal with a slight pink color. Bismuth is usually mixed with other metals, such as lead, tin, iron or cadmium to form low-melting alloys. These alloys are used in such things as automatic fire sprinkler systems, fire detection systems and electrical fuses.

Bismuth oxide (Bi2O3), a bismuth compound, is used as a yellow pigment in paints and cosmetics. Bismuth oxychloride (BiOCl) is used to make a pigment known as bismuth white. Bismuth carbonate (Bi2(CO3)3) is used to treat diarrhea and gastric ulcers.

Once thought to be the heaviest stable isotope to exist in nature, experiments conducted in 2002 showed that bismuth-209 is unstable and decays into thallium-205 through alpha decay. Bismuth-209 has a half-life of roughly 19,000,000,000,000,000,000 years.

"Bismanol" is a permanent magnet of high coercive force, made of MnBi, by the U.S. Naval Surface Weapons Center. Bismuth expands 3.32% on solidification. This property makes bismuth alloys particularly suited to the making of sharp castings of objects subject to damage by high temperatures. With other metals such as tin, cadmium, etc., bismuth forms low-melting alloys which are extensively used for safety devices in fire detection and extinguishing systems. Bismuth is used in producing malleable irons and is finding use as a catalyst for making acrylic fibers. When bismuth is heated in air it burns with a blue flame, forming yellow fumes of the oxide. The metal is also used as a thermocoupling material, and has found application as a carrier for 235U or 233U fuel in nuclear reactors. Its soluble salts are characterized by forming unsoluble basic salts on the addition of water, a property sometimes used in detection work. Bismuth oxychloride is used extensively in cosmetics. Bismuth subnitrate and subcarbonate are used in medicine.

Sources

The most important ores are bismuthinite or bismuth glance and bismite. Peru, Japan, Mexico, Bolivia, and Canada are major bismuth producers. Much of the bismuth produced in the U.S. is obtained as a by-product in refining lead, copper, tin, silver, and gold ores.

Compounds

See more information at the Bismuth compound page.

Element Forms

CID Name Formula SMILES Molecular Weight
5359367 bismuth Bi [Bi] 208.98040
105143 bismuth(3+) Bi+3 [Bi+3] 208.98040
6328547 bismuth-210 Bi [210Bi] 209.98412
6328549 bismuth-214 Bi [214Bi] 213.9987
6335500 bismuth-212 Bi [212Bi] 211.99129
6335818 bismuth-207 Bi [207Bi] 206.97847
6336623 bismuth-206 Bi [206Bi] 205.97850
6337093 bismuth-213 Bi [213Bi] 212.99438
6337623 bismuth-205 Bi [205Bi] 204.97739
6337532 bismuth-200 Bi [200Bi] 199.9781
6337548 bismuth-202 Bi [202Bi] 201.9777
6337577 bismuth-211 Bi [211Bi] 210.98727
6337633 bismuth-203 Bi [203Bi] 202.9769
6337620 bismuth-201 Bi [201Bi] 200.9770
16048797 bismuth-209 Bi [209Bi] 208.98040
130476802 bismuth(2+) Bi+2 [Bi+2] 208.98040
9813166 bismuth-213(3+) Bi+3 [213Bi+3] 212.99438
11701310 bismuth-216 Bi [216Bi] 216.0063
44148263 bismuth-208 Bi [208Bi] 207.97974
73456766 bismuth-198 Bi [198Bi] 197.9792
75124216 bismuth-192 Bi [192Bi] 191.9855
75124217 bismuth-194 Bi [194Bi] 193.98280
75124266 bismuth-196 Bi [196Bi] 195.9807
135474617 bismuth-217 Bi [217Bi] 217.0094

Isotopes

Stable Isotope Count 0

Isotopes in Medicine

212Bi and 213Bi (with half-lives of 1 h and 0.76 h, respectively) are both used in medicine for radioimmunotherapy as bismuth-labeled monoclonal antibodies to treat cancer cells from melanoma (skin cancer) (Fig. IUPAC.83.1) and ovarian cancer [559]. Figure 4.83.2 compares the biologic effect of 131I and 213Bi using a specific monoclonal antibody, B-B4, coupled to 213Bi by a chelating agent (a substance that can form multiple bonds to a single metal ion). 213Bi is a mixed alpha and beta emitter with a half-life of 0.76 h. The primary mode of decay is by beta emission to the very short-lived alpha emitter 213Po. The 8.4 MeV alpha particle emitted by 213Po has a path length of 76 μm in human tissue and is responsible for its cytotoxic effects (toxic to living cells). 213Bi is produced from a series of alpha particle decays beginning with 225Ac, which is a pure alpha emitter with a half-life of 10 days. A schematic of the Institute for Transuranium Elements (ITU) Standard 225Ac/ 213Bi Radionuclide Generator is shown in Fig. IUPAC.83.3.

212Bi has been used for radioimmunotherapy of leukemia and for targeting the vascular endothelial cells (thin layer of simple squamous cells that forms the interface between circulating blood or lymph and the remainder of the vessel wall) of tumors [560].

Fig. IUPAC.83.1: Melanoma (skin cancer) on a patient’s foot. ²¹²Bi and ²¹³Bi are both used as bismuth-labeled monoclonal antibodies to treat cancer cells from melanoma. (Photo Source: Kelly Nelson, National Cancer Institute) [561].

Fig. IUPAC.83.2: Comparison of biological effectiveness of ²¹³Bi and ¹³¹I when coupled to the specific monoclonal antibody B-B4 (modified after [562]); MBq/L, million becquerel per litre.

Fig. IUPAC.83.3: Schematic of the Institute for Transuranium Elements (ITU) Standard ²²⁵Ac/ ²¹³Bi Radionuclide Generator. Image kindly provided by Dr. Alfred Morgenstern, European Commission, Joint Research Centre – Institute for Transuranium Elements, Karlsruhe, Germany.

[559] D. E. Milenic, M. Roselli, S. Mirzadeh, C. G. Pippin, O. A. Gansow, D. Colcher, M. W. Brechbiel, J. Schlom. Cancer Biother. Radiopharm.16, 133 (2001).
[560] F. Hartmann, E. M. Horak, K. Garmestani, C. Wu, M. W. Brechbiel, R. W. Kozak, J. Tso, S. A. Kosteiny, O. A. Gansow, D. L. Nelson. Cancer Res.54, 4362 (1994).
[561] National Cancer Institute, Skin Cancer, Melanoma, Foot. https://visualsonline.cancer.gov/details.cfm?imageid=9246.
[562] S. Supiot, A. Faivre-Chauvet, O. Couturier, M. F. Heymann, N. Robillard, F. Kraeber-Bodéré, L. Morandeau, M. A. Mahé, M. Chérel. Cancer94, 1202 (2002).

Isotopes Used as a Source of Radioactive Isotope(s)

209Bi is bombarded with neutrons in a nuclear reactor to form radioactive 210Bi. The 210Bi (with a half-life of 5 days) decays via the reaction 210Bi→ 210Po+β −. The half-life of 210Po is 138 days and it is used in static eliminators in machinery [75].

[75] J. Peterson, M. McDonell, L. Haroun, F. Monette, R. D. Hildebrand, A. Taboas. Radiological and Chemical Fact Sheets to Support Health Risk Analyses for Contaminated Areas, Prepared by Argonne National Laboratory Environmental Science Division in collaboration with U.S. Department of Energy, Richland Operations Office and Chicago Operations Office (2014), Feb. 22; http://www.remm.nlm.gov/ANL_ContaminantFactSheets_All_070418.pdf.

Isotope Mass and Abundance

Isotope Atomic Mass (uncertainty) [u] Abundance (uncertainty)
209Bi 208.980 40(1) 1
Isotope Atomic Mass (uncertainty) [u] Abundance (uncertainty)
209Bi 208.9803991(16) 1

Atomic Mass, Half Life, and Decay

Nuclide Atomic Mass and Uncertainty [u] Half Life and Uncertainty Discovery Year Decay Modes, Intensities and Uncertainties [%]
184Bi 184.001347 ± 0.000131 [Estimated] 6.6 ms ± 1.5 2003 α=100%
184Bim 184.001347 ± 0.000131 [Estimated] 13 ms ± 2 2002 α=100%
185Bi 184.997600 ± 0.000087 [Estimated] 2 ms [Estimated] 1996 p ?; α ?
185Bim 184.997600 ± 0.000087 [Estimated] 58 us ± 4 1996 p=90±0.2%; α=10±0.2%
185Bin 184.997600 ± 0.000087 [Estimated] 50 us ± 10 2004 p=?; α=?
186Bi 185.996623169 ± 0.0000182 14.8 ms ± 0.7 1997 α≈100%; β+=?; β+SF≈0.011%
186Bim 185.996623169 ± 0.0000182 9.8 ms ± 0.4 1984 α≈100%; β+=?; β+SF≈0.011%
187Bi 186.993147272 ± 0.00001074 37 ms ± 2 1999 α=100%
187Bim 186.993147272 ± 0.00001074 370 us ± 20 1984 α=100%
187Bin 186.993147272 ± 0.00001074 7 us ± 5 2002 IT=100%
188Bi 187.992276064 ± 0.000012001 60 ms ± 3 1980 α≈100%; β+ ?; β+SF=0.0014±0.7%
188Bim 187.992276064 ± 0.000012001 >5 us 1984 IT ?; α ?; β+ ?
188Bin 187.992276064 ± 0.000012001 265 ms ± 15 1984 α≈100%; β+ ?; β+SF=0.0046±0.9%
189Bi 188.989195139 ± 0.000022384 688 ms ± 5 1973 α≈100%; β+ ?
189Bim 188.989195139 ± 0.000022384 5.0 ms ± 0.1 1984 α=83±0.5%; IT=17±0.5%
189Bin 188.989195139 ± 0.000022384 880 ns ± 50 2001 IT=100%
190Bi 189.988624828 ± 0.000022515 6.3 s ± 0.1 1972 α=77±2.1%; β+=23±2.1%; β+SF=6e-6±0.5%
190Bim 189.988624828 ± 0.000022515 6.2 s ± 0.1 1988 α=70±0.9%; β+ ?; β+SF=4e-6±0.3%
190Bin 189.988624828 ± 0.000022515 175 ns ± 8 2009 IT=100%
190Bip 189.988624828 ± 0.000022515 1.3 us ± 0.8 2001 IT=100%
191Bi 190.985786972 ± 0.000008037 12.4 s ± 0.3 1972 α=51±1%; β+ ?
191Bim 190.985786972 ± 0.000008037 125 ms ± 8 1981 α=68±0.5%; IT ?; β+ ?
191Bin 190.985786972 ± 0.000008037 562 ns ± 10 2001 IT=100%
191Bip 190.985786972 ± 0.000008037 400 ns ± 40 2016 IT=100%
192Bi 191.985470077 ± 0.000032326 34.6 s ± 0.9 1971 β+=88±0.5%; α=12±0.5%
192Bim 191.985470077 ± 0.000032326 39.6 s ± 0.4 1966 β+=90±0.3%; α=10±0.3%
193Bi 192.982947220 ± 0.000008132 63.6 s ± 3.0 1971 β+=96.5±1.5%; α=3.5±1.5%
193Bim 192.982947220 ± 0.000008132 3.20 s ± 0.14 1970 α=84±1.6%; β+ ?
193Bin 192.982947220 ± 0.000008132 153 ns ± 10 2004 IT=100%
193Bip 192.982947220 ± 0.000008132 85 us ± 3 2004 IT=100%
193Biq 192.982947220 ± 0.000008132 3.02 us ± 0.08 2004 IT=100%
194Bi 193.982798581 ± 0.000005638 95 s ± 3 1971 β+≈100%; α=0.46±2.5%
194Bim 193.982798581 ± 0.000005638 125 s ± 2 1976 β+≈100%; α ?
194Bin 193.982798581 ± 0.000005638 115 s ± 4 1988 β+≈100%; α=0.20±0.7%
195Bi 194.980648759 ± 0.000005675 183 s ± 4 1971 β+≈100%; α=0.030±1.2%
195Bim 194.980648759 ± 0.000005675 87 s ± 1 1974 β+=67±1.7%; α=33±1.7%
195Bin 194.980648759 ± 0.000005675 614 ns ± 5 2003 IT=100%
195Bip 194.980648759 ± 0.000005675 1.49 us ± 0.01 2018 IT=100%
196Bi 195.980666509 ± 0.000026224 5.13 m ± 0.20 1976 β+≈100%; α=0.00115±3.4%
196Bim 195.980666509 ± 0.000026224 0.6 s ± 0.5 1987 IT≈100%; β+ ?
196Bin 195.980666509 ± 0.000026224 4.00 m ± 0.05 1987 β+=74.2±2.5%; IT=25.8±2.5%; α=0.00038±1%
197Bi 196.978864927 ± 0.000008946 9.33 m ± 0.50 1971 β+=100%; α ?
197Bim 196.978864927 ± 0.000008946 5.04 m ± 0.16 1966 α=55±4%; β+=45±4%; IT ?
197Bin 196.978864927 ± 0.000008946 204 ns ± 18 IT=100%
197Bip 196.978864927 ± 0.000008946 263 ns ± 13 1986 IT=100%
197Biq 196.978864927 ± 0.000008946 209 ns ± 30 1986 IT=100%
198Bi 197.979201316 ± 0.000029598 10.3 m ± 0.3 1950 β+=100%
198Bim 197.979201316 ± 0.000029598 11.6 m ± 0.3 1992 β+=100%
198Bin 197.979201316 ± 0.000029598 7.7 s ± 0.5 1972 IT=100%
199Bi 198.977672841 ± 0.000011395 27 m ± 1 1950 β+=100%
199Bim 198.977672841 ± 0.000011395 24.70 m ± 0.15 1950 β+=?; IT<2%; α≈0.01%
199Bin 198.977672841 ± 0.000011395 100 ns ± 30 1974 IT=100%
199Bip 198.977672841 ± 0.000011395 168 ns ± 13 1985 IT=100%
200Bi 199.978131290 ± 0.00002437 36.4 m ± 0.5 1950 β+=100%
200Bim 199.978131290 ± 0.00002437 31 m ± 2 1978 β+<100%; IT ?
200Bin 199.978131290 ± 0.00002437 400 ms ± 50 1972 IT=100%
201Bi 200.976995017 ± 0.000013072 103 m ± 3 1950 β+=100%
201Bim 200.976995017 ± 0.000013072 57.5 m ± 2.1 1950 β+≈100%; α=?; IT ?
201Bin 200.976995017 ± 0.000013072 118 ns ± 28 1982 IT=100%
201Bip 200.976995017 ± 0.000013072 105 ns ± 75 1985 IT=100%
201Biq 200.976995017 ± 0.000013072 124 ns ± 4 1982 IT=100%
202Bi 201.977723042 ± 0.000015032 1.72 h ± 0.05 1951 β+=100%; α<1e-5%
202Bim 201.977723042 ± 0.000015032 3.04 us ± 0.06 1981 IT=100%
202Bin 201.977723042 ± 0.000015032 310 ns ± 50 1981 IT=100%
203Bi 202.976892077 ± 0.000013717 11.76 h ± 0.05 1950 β+=100%
203Bim 202.976892077 ± 0.000013717 305 ms ± 5 1984 IT=100%
203Bin 202.976892077 ± 0.000013717 194 ns ± 30 1978 IT=100%
204Bi 203.977835687 ± 0.000009854 11.22 h ± 0.10 1947 β+=100%
204Bim 203.977835687 ± 0.000009854 13.0 ms ± 0.1 1974 IT=100%
204Bin 203.977835687 ± 0.000009854 1.07 ms ± 0.03 1974 IT=100%
205Bi 204.977385182 ± 0.000005161 14.91 d ± 0.07 1951 β+=100%
205Bim 204.977385182 ± 0.000005161 7.9 us ± 0.7 1972 IT=100%
205Bin 204.977385182 ± 0.000005161 100 ns ± 6 1978 IT=100%
205Bip 204.977385182 ± 0.000005161 220 ns ± 25 1978 IT=100%
206Bi 205.978498843 ± 0.000008193 6.243 d ± 0.003 1947 β+=100%
206Bim 205.978498843 ± 0.000008193 7.7 us ± 0.2 1957 IT=100%
206Bin 205.978498843 ± 0.000008193 890 us ± 10 1974 IT=100%
206Bip 205.978498843 ± 0.000008193 155 ns ± 15 2012 IT=100%
206Biq 205.978498843 ± 0.000008193 >2 us 2012 IT=100%
207Bi 206.978470551 ± 0.000002573 31.22 y ± 0.17 1950 β+=100%
207Bim 206.978470551 ± 0.000002573 182 us ± 6 1967 IT=100%
208Bi 207.979742060 ± 0.000002474 368 ky ± 4 1953 β+=100%
208Bim 207.979742060 ± 0.000002474 2.58 ms ± 0.04 1961 IT=100%
209Bi 208.980398599 ± 0.000001465 20.1 Ey ± 0.8 1924 IS=100%; α=100%
210Bi 209.984120237 ± 0.000001463 5.012 d ± 0.005 1905 β-=100%; α=13.2e-5±1%
210Bim 209.984120237 ± 0.000001463 3.04 My ± 0.06 1953 α=100%
211Bi 210.987268715 ± 0.000005842 2.14 m ± 0.02 1905 α≈100%; β-=0.276±0.4%
211Bim 210.987268715 ± 0.000005842 1.4 us ± 0.3 1998 IT=100%
212Bi 211.991285030 ± 0.000001989 60.55 m ± 0.06 1905 β-=64.06±0.6%; α=35.94±0.6%; β-α≈0.014%
212Bim 211.991285030 ± 0.000001989 25.0 m ± 0.2 1978 α=67±0.1%; β-=33±0.1%; β-α=30±0.1%
212Bin 211.991285030 ± 0.000001989 7.0 m ± 0.3 1978 β-=?; IT ?
213Bi 212.994383570 ± 0.000005455 45.60 m ± 0.04 1947 β-=97.91±0.3%; α=2.09±0.3%
213Bim 212.994383570 ± 0.000005455 >168 s 2008 β- ?; IT ?
214Bi 213.998710909 ± 0.000012033 19.9 m ± 0.4 1904 β-=99.979±0.1%; α=0.021±0.1%; β-α≈0.003%
214Bim 213.998710909 ± 0.000012033 >93 s 2008 β+ ?; IT ?
215Bi 215.001749095 ± 0.000006037 7.62 m ± 0.13 1953 β-=100%
215Bim 215.001749095 ± 0.000006037 36.9 s ± 0.6 2001 IT=76.9±0.5%; β-=23.1±0.5%
216Bi 216.006305985 ± 0.000012 2.21 m ± 0.04 1989 β-=100%
216Bim 216.006305985 ± 0.000012 6.6 m ± 2.1 1989 β-=100%
217Bi 217.009372000 ± 0.000019 98.5 s ± 1.3 1998 β-=100%
217Bim 217.009372000 ± 0.000019 3.0 us ± 0.2 2012 IT=100%
218Bi 218.014188000 ± 0.000029 33 s ± 1 1998 β-=100%
219Bi 219.017520 ± 0.000215 [Estimated] 8.7 s ± 2.9 2009 β-=100%; β-n ?
220Bi 220.022501 ± 0.000322 [Estimated] 9.5 s ± 5.7 2010 β-=100%; β-n ?
221Bi 221.025980 ± 0.000322 [Estimated] 2 s >300ns [Estimated] 2009 β- ?; β-n ?
222Bi 222.031079 ± 0.000322 [Estimated] 3 s >300ns [Estimated] 2009 β- ?; β-n ?
223Bi 223.034611 ± 0.000429 [Estimated] 1 s >300ns [Estimated] 2009 β- ?; β-n ?
224Bi 224.039796 ± 0.000429 [Estimated] 1 s >300ns [Estimated] 2010 β- ?; β-n ?

Information Sources

  1. 1.  PubChem
  2. 2.  Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
  3. 3.  IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
  4. 4.  Jefferson Lab, U.S. Department of Energy
    LICENSE
    Please see citation and linking information https https://www.jlab.org/privacy-and-security-notice
  5. 5.  Los Alamos National Laboratory, U.S. Department of Energy
  6. 6.  NIST Physical Measurement Laboratory
  7. 7.  IUPAC Periodic Table of the Elements and Isotopes (IPTEI)
    LICENSE
    Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
    https://creativecommons.org/licenses/by-nc-nd/4.0/
  8. 8.  PubChem Elements
    Bismuth

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