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Phosphorus tribromide - ≥99.99% metals basis, high purity , CAS No.7789-60-8

17 Citations

PrimorTrace™

≥99.99% metals basis

CAS#: 7789-60-8
Molecular Weight: 270.69
EC Number: 232-178-2
MDL number: MFCD00011436
PubChem CID: 24614

Item Number

P108401

Grouped product items
SKU	Size	Availability	Price
P108401-10g	10g	2	$58.90
P108401-50g	50g	3	$194.90
P108401-250g	250g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$876.90

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Halogenating reagent (0)

Basic Description

Synonyms	Phosphorus(III) bromide \| PHOSPHORUS TRIBROMIDE [HSDB] \| 58R3866PUA \| Br3P \| A839279 \| Phosphorous tribromide \| Phosphorous bromide \| HSDB 1217 \| Phosphorus tribromide, 99% \| AKOS015856778 \| Phosphorus(III) tribromide \| Tribromo phosphine \| tribromophosph
Specifications & Purity	PrimorTrace™, ≥99.99% metals basis
Storage Temp	Argon charged
Shipped In	Normal
Grade	PrimorTrace™
Product Description	Phosphorus tribromide (PBr3) is commonly used in Hell-Volhard-Zelinsky halogenation for the α-bromination of carboxylic acids to form the corresponding acyl bromide. It is also useful for the conversion of primary and secondary alcohols to alkyl bromides. Phosphorus tribromide may be used as a reagent: · In a novel protocol for synthesizing 7-ethoxy-1-(p-ethylphenoxy)-3,7-dimethyl-2-octene, a synthetic juvenile hormone mimic of trans,trans,cis-10,11-epoxy-7-ethyl-3,11-dimethyltrideca-2,6-dienoate. · To synthesize 1,2,3-diazaphosphinane, 1,2,3-thiazaphosphinine and 1,2-azaphosphole bearing a chromone ring. · To synthesize 1-Bromoundec-1-ene from 10-undecen-1-ol.

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Names and Identifiers

IUPAC Name	tribromophosphane
INCHI	InChI=1S/Br3P/c1-4(2)3
InChi Key	IPNPIHIZVLFAFP-UHFFFAOYSA-N
Canonical SMILES	P(Br)(Br)Br
Isomeric SMILES	P(Br)(Br)Br
WGK Germany	2
RTECS	TH4460000
PubChem CID	24614
UN Number	1808
Packing Group	II
Molecular Weight	270.69

Certificates（CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):

Analytical Chart:

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14 results found

Lot Number	Certificate Type	Date	Item
C2507611	Certificate of Analysis	Mar 18, 2025	P108401
C2507612	Certificate of Analysis	Mar 18, 2025	P108401
D2326947	Certificate of Analysis	Jan 06, 2025	P108401
D2326952	Certificate of Analysis	Jan 06, 2025	P108401
D2326957	Certificate of Analysis	Jan 06, 2025	P108401
J2415838	Certificate of Analysis	Sep 23, 2024	P108401
J2415867	Certificate of Analysis	Sep 23, 2024	P108401
H2231610	Certificate of Analysis	Jun 19, 2024	P108401
H2231611	Certificate of Analysis	Jun 19, 2024	P108401
C2210589	Certificate of Analysis	Dec 19, 2023	P108401
F1808098	Certificate of Analysis	Nov 16, 2023	P108401
G2121155	Certificate of Analysis	Apr 18, 2023	P108401
D2326951	Certificate of Analysis	Apr 18, 2023	P108401
G2121156	Certificate of Analysis	Apr 18, 2023	P108401

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Safety and Hazards(GHS)

Pictogram(s)	GHS05, GHS07
Signal	Danger
Hazard Statements	H335:May cause respiratory irritation H314:Causes severe skin burns and eye damage
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P271:Use only outdoors or in a well-ventilated area. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363:Wash contaminated clothing before reuse. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P304+P340+P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or doctor. if you feel unwell.
WGK Germany	2
RTECS	TH4460000
Class	8
Merck Index	7357

Alternative Products

Reviews

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Yayuan Liu, Fuyue Tian, Jing Hu, Nanying Ning, Bing Yu, Ming Tian. (2023) Photochromic Polyurethane Coatings with Cross-Linked Structure and Self-Healing Behavior Based on the FRET Effect. MACROMOLECULAR RAPID COMMUNICATIONS, 44 (13): (2300097). [PMID:37165710] [10.1002/marc.202300097]
2. Yan Zhao, Xinquan Yu, Xiao Liu, Dailiang Zhang, He Li, Hanlin Zhou, Weiheng Kong, Fengli Qu. (2023) ClO– Induced Dual-Excitation Fluorescent Probes Responding to Diverse Testing Modes with Ratio Methodology. ANALYTICAL CHEMISTRY, 95 (18): (7170–7177). [PMID:37114482] [10.1021/acs.analchem.2c05532]
3. Cheng Deng, Hai Yang, Simin Liu, Zhiyong Zhao. (2023) Self-assembly of Dendrimer-DNA amphiphiles and their catalysis as G-quadruplex/hemin DNAzymes. POLYMER, 266 (125621). [PMID:] [10.1016/j.polymer.2022.125621]
4. Ling Yan, Qing-Song Gu, Wen-Li Jiang, Min Tan, Zhi-Ke Tan, Guo-Jiang Mao, Fen Xu, Chun-Yan Li. (2022) Near-Infrared Fluorescent Probe with Large Stokes Shift for Imaging of Hydrogen Sulfide in Tumor-Bearing Mice. ANALYTICAL CHEMISTRY, 94 (14): (5514–5520). [PMID:35360906] [10.1021/acs.analchem.1c04169]
5. Junjun Wang, Yize Zhang, Zhi-Peng Yu, Houshi Huang, Lei Chen, Xiaojiao Zhu, Jie Zhang, Lianke Wang, Jianhua Yu, Hongping Zhou. (2021) Diversified photo-energy conversion based on single-molecule FRET to realize enhanced phototheranostics. Materials Chemistry Frontiers, 5 (23): (8229-8237). [PMID:] [10.1039/D1QM01105G]
6. Yongchao Yao, Yunlong Yu, Xiaohui Wan, Daoping Yan, Ying Chen, Jianbin Luo, G. Julius Vancso, Shiyong Zhang. (2021) Azobenzene-Based Cross-Linked Small-Molecule Vesicles for Precise Oxidative Damage Treatments Featuring Controlled and Prompt Molecular Release. CHEMISTRY OF MATERIALS, 33 (18): (7357–7366). [PMID:] [10.1021/acs.chemmater.1c01860]
7. Tingting Zheng, Yujie Zhu, Anwei Zhu. (2021) Boronic Acid-containing Stimuli-responsive Polymers Modified Nanopores for Label-free Dual-signal-output Detection of Glucose. ELECTROANALYSIS, 34 (2): (326-331). [PMID:] [10.1002/elan.202100268]
8. Yao Zhu, Yue Qi, Xinghua Guo, Meicheng Zhang, Zhimin Jia, Chuanqin Xia, Ning Liu, Chiyao Bai, Lijian Ma, Qin Wang. (2021) A crystalline covalent organic framework embedded with a crystalline supramolecular organic framework for efficient iodine capture. Journal of Materials Chemistry A, 9 (31): (16961-16966). [PMID:] [10.1039/D1TA03879F]
9. Shuifang Mao, Bin Wang, Lin Yue, Wenshui Xia. (2021) Effects of citronellol grafted chitosan oligosaccharide derivatives on regulating anti-inflammatory activity. CARBOHYDRATE POLYMERS, 262 (117972). [PMID:33838788] [10.1016/j.carbpol.2021.117972]
10. Yang Tian, Dong-Ye Zhou, Wen-Li Jiang, Zun-Pan She, Yongfei Li, Chun-Yan Li. (2021) Novel near-infrared fluorescence probe with large Stokes shift for monitoring CCl4-induced toxic hepatitis. TALANTA, 223 (121720). [PMID:33303166] [10.1016/j.talanta.2020.121720]
11. Xulin Lu, Xian-Fu Zhang. (2020) Phosphorous tetrabenzocorrolazine from its metal-free phthalocyanine precursor: Its facile synthesis, high fluorescence emission, efficient singlet oxygen formation, and promising hole transporting material. DYES AND PIGMENTS, 179 (108421). [PMID:] [10.1016/j.dyepig.2020.108421]
12. Fulei Liu, Xiaoxian Huang, Lingfei Han, Mangmang Sang, Lejian Hu, Bowen Liu, Bingjing Duan, Pan Jiang, Xin Wang, Zhou Qiao, Congyu Ma, Wenyuan Liu, Jun Liu, Feng Feng, Wei Qu. (2019) Improved druggability of gambogic acid using core–shell nanoparticles. Biomaterials Science, 7 (3): (1028-1042). [PMID:30608065] [10.1039/C8BM01154K]
13. Lingfei Han, Lejian Hu, Fulei Liu, Xin Wang, Xiaoxian Huang, Bowen Liu, Feng Feng, Wenyuan Liu, Wei Qu. (2019) Redox-sensitive micelles for targeted intracellular delivery and combination chemotherapy of paclitaxel and all-trans-retinoid acid. Asian Journal of Pharmaceutical Sciences, 14 (531). [PMID:32104480] [10.1016/j.ajps.2018.08.009]
14. Mo Zhu, Nairong Hao, Jinxian Yang, Lianwei Li. (2018) A comparative study of intrachain cyclization and solution properties of long-subchain hyperbranched polymers prepared via Y-type and V-type macromonomer approaches. Polymer Chemistry, 9 (20): (2830-2842). [PMID:] [10.1039/C8PY00362A]
15. Bowen Li, Peilian Liu, Hao Wu, Xin Xie, Zelin Chen, Fang Zeng, Shuizhu Wu. (2017) A bioorthogonal nanosystem for imaging and in vivo tumor inhibition. BIOMATERIALS, 138 (57). [PMID:28554008] [10.1016/j.biomaterials.2017.05.036]
16. Bin Jiang, Zhaohe Huang, Luhong Zhang, Yongli Sun, Huawei Yang, Hanrong Bi. (2016) Highly efficient and reversible CO2 capture by imidazolate-based ether-functionalized ionic liquids with a capture transforming process. Journal of the Taiwan Institute of Chemical Engineers, 69 (85). [PMID:] [10.1016/j.jtice.2016.10.009]
17. Keyi Wang, Yingzhuang Chen, Huihui Yang, Yi Li, Lihua Nie, Shouzhuo Yao. (2012) Modification of VTMS hybrid monolith via thiol-ene click chemistry for capillary electrochromatography. TALANTA, 91 (52). [PMID:22365679] [10.1016/j.talanta.2012.01.009]

References

1. Yayuan Liu, Fuyue Tian, Jing Hu, Nanying Ning, Bing Yu, Ming Tian. (2023) Photochromic Polyurethane Coatings with Cross-Linked Structure and Self-Healing Behavior Based on the FRET Effect. MACROMOLECULAR RAPID COMMUNICATIONS, 44 (13): (2300097). [PMID:37165710] [10.1002/marc.202300097]
2. Yan Zhao, Xinquan Yu, Xiao Liu, Dailiang Zhang, He Li, Hanlin Zhou, Weiheng Kong, Fengli Qu. (2023) ClO– Induced Dual-Excitation Fluorescent Probes Responding to Diverse Testing Modes with Ratio Methodology. ANALYTICAL CHEMISTRY, 95 (18): (7170–7177). [PMID:37114482] [10.1021/acs.analchem.2c05532]
3. Cheng Deng, Hai Yang, Simin Liu, Zhiyong Zhao. (2023) Self-assembly of Dendrimer-DNA amphiphiles and their catalysis as G-quadruplex/hemin DNAzymes. POLYMER, 266 (125621). [PMID:] [10.1016/j.polymer.2022.125621]
4. Ling Yan, Qing-Song Gu, Wen-Li Jiang, Min Tan, Zhi-Ke Tan, Guo-Jiang Mao, Fen Xu, Chun-Yan Li. (2022) Near-Infrared Fluorescent Probe with Large Stokes Shift for Imaging of Hydrogen Sulfide in Tumor-Bearing Mice. ANALYTICAL CHEMISTRY, 94 (14): (5514–5520). [PMID:35360906] [10.1021/acs.analchem.1c04169]
5. Junjun Wang, Yize Zhang, Zhi-Peng Yu, Houshi Huang, Lei Chen, Xiaojiao Zhu, Jie Zhang, Lianke Wang, Jianhua Yu, Hongping Zhou. (2021) Diversified photo-energy conversion based on single-molecule FRET to realize enhanced phototheranostics. Materials Chemistry Frontiers, 5 (23): (8229-8237). [PMID:] [10.1039/D1QM01105G]
6. Yongchao Yao, Yunlong Yu, Xiaohui Wan, Daoping Yan, Ying Chen, Jianbin Luo, G. Julius Vancso, Shiyong Zhang. (2021) Azobenzene-Based Cross-Linked Small-Molecule Vesicles for Precise Oxidative Damage Treatments Featuring Controlled and Prompt Molecular Release. CHEMISTRY OF MATERIALS, 33 (18): (7357–7366). [PMID:] [10.1021/acs.chemmater.1c01860]
7. Tingting Zheng, Yujie Zhu, Anwei Zhu. (2021) Boronic Acid-containing Stimuli-responsive Polymers Modified Nanopores for Label-free Dual-signal-output Detection of Glucose. ELECTROANALYSIS, 34 (2): (326-331). [PMID:] [10.1002/elan.202100268]
8. Yao Zhu, Yue Qi, Xinghua Guo, Meicheng Zhang, Zhimin Jia, Chuanqin Xia, Ning Liu, Chiyao Bai, Lijian Ma, Qin Wang. (2021) A crystalline covalent organic framework embedded with a crystalline supramolecular organic framework for efficient iodine capture. Journal of Materials Chemistry A, 9 (31): (16961-16966). [PMID:] [10.1039/D1TA03879F]
9. Shuifang Mao, Bin Wang, Lin Yue, Wenshui Xia. (2021) Effects of citronellol grafted chitosan oligosaccharide derivatives on regulating anti-inflammatory activity. CARBOHYDRATE POLYMERS, 262 (117972). [PMID:33838788] [10.1016/j.carbpol.2021.117972]
10. Yang Tian, Dong-Ye Zhou, Wen-Li Jiang, Zun-Pan She, Yongfei Li, Chun-Yan Li. (2021) Novel near-infrared fluorescence probe with large Stokes shift for monitoring CCl4-induced toxic hepatitis. TALANTA, 223 (121720). [PMID:33303166] [10.1016/j.talanta.2020.121720]
11. Xulin Lu, Xian-Fu Zhang. (2020) Phosphorous tetrabenzocorrolazine from its metal-free phthalocyanine precursor: Its facile synthesis, high fluorescence emission, efficient singlet oxygen formation, and promising hole transporting material. DYES AND PIGMENTS, 179 (108421). [PMID:] [10.1016/j.dyepig.2020.108421]
12. Fulei Liu, Xiaoxian Huang, Lingfei Han, Mangmang Sang, Lejian Hu, Bowen Liu, Bingjing Duan, Pan Jiang, Xin Wang, Zhou Qiao, Congyu Ma, Wenyuan Liu, Jun Liu, Feng Feng, Wei Qu. (2019) Improved druggability of gambogic acid using core–shell nanoparticles. Biomaterials Science, 7 (3): (1028-1042). [PMID:30608065] [10.1039/C8BM01154K]
13. Lingfei Han, Lejian Hu, Fulei Liu, Xin Wang, Xiaoxian Huang, Bowen Liu, Feng Feng, Wenyuan Liu, Wei Qu. (2019) Redox-sensitive micelles for targeted intracellular delivery and combination chemotherapy of paclitaxel and all-trans-retinoid acid. Asian Journal of Pharmaceutical Sciences, 14 (531). [PMID:32104480] [10.1016/j.ajps.2018.08.009]
14. Mo Zhu, Nairong Hao, Jinxian Yang, Lianwei Li. (2018) A comparative study of intrachain cyclization and solution properties of long-subchain hyperbranched polymers prepared via Y-type and V-type macromonomer approaches. Polymer Chemistry, 9 (20): (2830-2842). [PMID:] [10.1039/C8PY00362A]
15. Bowen Li, Peilian Liu, Hao Wu, Xin Xie, Zelin Chen, Fang Zeng, Shuizhu Wu. (2017) A bioorthogonal nanosystem for imaging and in vivo tumor inhibition. BIOMATERIALS, 138 (57). [PMID:28554008] [10.1016/j.biomaterials.2017.05.036]
16. Bin Jiang, Zhaohe Huang, Luhong Zhang, Yongli Sun, Huawei Yang, Hanrong Bi. (2016) Highly efficient and reversible CO2 capture by imidazolate-based ether-functionalized ionic liquids with a capture transforming process. Journal of the Taiwan Institute of Chemical Engineers, 69 (85). [PMID:] [10.1016/j.jtice.2016.10.009]
17. Keyi Wang, Yingzhuang Chen, Huihui Yang, Yi Li, Lihua Nie, Shouzhuo Yao. (2012) Modification of VTMS hybrid monolith via thiol-ene click chemistry for capillary electrochromatography. TALANTA, 91 (52). [PMID:22365679] [10.1016/j.talanta.2012.01.009]

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