| SKU | Size | Availability | Price | Qty |
|---|---|---|---|---|
| P108402-100g | 100g | 3 | $54.90 | |
| P108402-500g | 500g | Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience! | $209.90 |
| Synonyms | Phosphorus(III) bromide | PHOSPHORUS TRIBROMIDE [HSDB] | 58R3866PUA | Br3P | A839279 | Phosphorous tribromide | Phosphorous bromide | HSDB 1217 | Phosphorus tribromide, 99% | AKOS015856778 | Phosphorus(III) tribromide | Tribromo phosphine | tribromophosph |
|---|---|
| Specifications & Purity | ≥99% |
| Storage Temp | Argon charged |
| Shipped In | Normal |
| Product Description | Phosphorus tribromide (PBr3) is commonly used in Hell-Volhard-Zelinsky halogenation for the α-bromination of carboxylic acids to form the corresponding acyl bromide. It is also useful for the conversion of primary and secondary alcohols to alkyl bromides. Phosphorus tribromide may be used as a reagent: · In a novel protocol for synthesizing 7-ethoxy-1-(p-ethylphenoxy)-3,7-dimethyl-2-octene, a synthetic juvenile hormone mimic of trans,trans,cis-10,11-epoxy-7-ethyl-3,11-dimethyltrideca-2,6-dienoate. · To synthesize 1,2,3-diazaphosphinane, 1,2,3-thiazaphosphinine and 1,2-azaphosphole bearing a chromone ring. · To synthesize 1-Bromoundec-1-ene from 10-undecen-1-ol. |
Find and download the COA for your product by matching the lot number on the packaging.
| Lot Number | Certificate Type | Date | Item |
|---|---|---|---|
 C2507610 | Certificate of Analysis | Mar 18, 2025 | P108402 |
| C2507609 | Certificate of Analysis | Mar 18, 2025 | P108402 |
| C2507594 | Certificate of Analysis | Mar 18, 2025 | P108402 |
| C2507593 | Certificate of Analysis | Mar 18, 2025 | P108402 |
| J2415864 | Certificate of Analysis | Oct 24, 2024 | P108402 |
| J2415865 | Certificate of Analysis | Oct 24, 2024 | P108402 |
| J2415862 | Certificate of Analysis | Oct 24, 2024 | P108402 |
| J2415866 | Certificate of Analysis | Oct 24, 2024 | P108402 |
| C2407339 | Certificate of Analysis | Mar 22, 2024 | P108402 |
| C2407337 | Certificate of Analysis | Mar 22, 2024 | P108402 |
| C2407241 | Certificate of Analysis | Mar 22, 2024 | P108402 |
| C2407238 | Certificate of Analysis | Mar 22, 2024 | P108402 |
| D2403608 | Certificate of Analysis | Mar 14, 2024 | P108402 |
| D2403611 | Certificate of Analysis | Mar 14, 2024 | P108402 |
| J2318648 | Certificate of Analysis | Oct 30, 2023 | P108402 |
| J2318694 | Certificate of Analysis | Oct 27, 2023 | P108402 |
| J2318649 | Certificate of Analysis | Oct 27, 2023 | P108402 |
| J2318650 | Certificate of Analysis | Oct 27, 2023 | P108402 |
| D2326951 | Certificate of Analysis | May 09, 2023 | P108402 |
| D2326956 | Certificate of Analysis | May 09, 2023 | P108402 |
| D2326953 | Certificate of Analysis | May 09, 2023 | P108402 |
| K2217991 | Certificate of Analysis | Nov 22, 2022 | P108402 |
| K2217972 | Certificate of Analysis | Nov 22, 2022 | P108402 |
| K2217978 | Certificate of Analysis | Nov 22, 2022 | P108402 |
| K2217940 | Certificate of Analysis | Nov 21, 2022 | P108402 |
| H2231920 | Certificate of Analysis | Sep 05, 2022 | P108402 |
| H2231796 | Certificate of Analysis | Sep 05, 2022 | P108402 |
| H2231794 | Certificate of Analysis | Sep 05, 2022 | P108402 |
| H2231793 | Certificate of Analysis | Sep 05, 2022 | P108402 |
| C2210497 | Certificate of Analysis | Mar 19, 2022 | P108402 |
| C2210478 | Certificate of Analysis | Mar 19, 2022 | P108402 |
| C2210429 | Certificate of Analysis | Mar 19, 2022 | P108402 |
| C2210428 | Certificate of Analysis | Mar 19, 2022 | P108402 |
| Pictogram(s) | GHS05, GHS07 |
|---|---|
| Signal | Danger |
| Hazard Statements | H335:May cause respiratory irritation H314:Causes severe skin burns and eye damage |
| Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P271:Use only outdoors or in a well-ventilated area. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363:Wash contaminated clothing before reuse. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P304+P340+P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or doctor. if you feel unwell. |
| WGK Germany | 2 |
| RTECS | TH4460000 |
| Class | 8 |
| Merck Index | 7357 |
| 1. Yayuan Liu, Fuyue Tian, Jing Hu, Nanying Ning, Bing Yu, Ming Tian. (2023) Photochromic Polyurethane Coatings with Cross-Linked Structure and Self-Healing Behavior Based on the FRET Effect. MACROMOLECULAR RAPID COMMUNICATIONS, 44 (13): (2300097). [PMID:37165710] [10.1002/marc.202300097] |
| 2. Yan Zhao, Xinquan Yu, Xiao Liu, Dailiang Zhang, He Li, Hanlin Zhou, Weiheng Kong, Fengli Qu. (2023) ClO– Induced Dual-Excitation Fluorescent Probes Responding to Diverse Testing Modes with Ratio Methodology. ANALYTICAL CHEMISTRY, 95 (18): (7170–7177). [PMID:37114482] [10.1021/acs.analchem.2c05532] |
| 3. Cheng Deng, Hai Yang, Simin Liu, Zhiyong Zhao. (2023) Self-assembly of Dendrimer-DNA amphiphiles and their catalysis as G-quadruplex/hemin DNAzymes. POLYMER, 266 (125621). [PMID:] [10.1016/j.polymer.2022.125621] |
| 4. Ling Yan, Qing-Song Gu, Wen-Li Jiang, Min Tan, Zhi-Ke Tan, Guo-Jiang Mao, Fen Xu, Chun-Yan Li. (2022) Near-Infrared Fluorescent Probe with Large Stokes Shift for Imaging of Hydrogen Sulfide in Tumor-Bearing Mice. ANALYTICAL CHEMISTRY, 94 (14): (5514–5520). [PMID:35360906] [10.1021/acs.analchem.1c04169] |
| 5. Junjun Wang, Yize Zhang, Zhi-Peng Yu, Houshi Huang, Lei Chen, Xiaojiao Zhu, Jie Zhang, Lianke Wang, Jianhua Yu, Hongping Zhou. (2021) Diversified photo-energy conversion based on single-molecule FRET to realize enhanced phototheranostics. Materials Chemistry Frontiers, 5 (23): (8229-8237). [PMID:] [10.1039/D1QM01105G] |
| 6. Yongchao Yao, Yunlong Yu, Xiaohui Wan, Daoping Yan, Ying Chen, Jianbin Luo, G. Julius Vancso, Shiyong Zhang. (2021) Azobenzene-Based Cross-Linked Small-Molecule Vesicles for Precise Oxidative Damage Treatments Featuring Controlled and Prompt Molecular Release. CHEMISTRY OF MATERIALS, 33 (18): (7357–7366). [PMID:] [10.1021/acs.chemmater.1c01860] |
| 7. Tingting Zheng, Yujie Zhu, Anwei Zhu. (2021) Boronic Acid-containing Stimuli-responsive Polymers Modified Nanopores for Label-free Dual-signal-output Detection of Glucose. ELECTROANALYSIS, 34 (2): (326-331). [PMID:] [10.1002/elan.202100268] |
| 8. Yao Zhu, Yue Qi, Xinghua Guo, Meicheng Zhang, Zhimin Jia, Chuanqin Xia, Ning Liu, Chiyao Bai, Lijian Ma, Qin Wang. (2021) A crystalline covalent organic framework embedded with a crystalline supramolecular organic framework for efficient iodine capture. Journal of Materials Chemistry A, 9 (31): (16961-16966). [PMID:] [10.1039/D1TA03879F] |
| 9. Shuifang Mao, Bin Wang, Lin Yue, Wenshui Xia. (2021) Effects of citronellol grafted chitosan oligosaccharide derivatives on regulating anti-inflammatory activity. CARBOHYDRATE POLYMERS, 262 (117972). [PMID:33838788] [10.1016/j.carbpol.2021.117972] |
| 10. Yang Tian, Dong-Ye Zhou, Wen-Li Jiang, Zun-Pan She, Yongfei Li, Chun-Yan Li. (2021) Novel near-infrared fluorescence probe with large Stokes shift for monitoring CCl4-induced toxic hepatitis. TALANTA, 223 (121720). [PMID:33303166] [10.1016/j.talanta.2020.121720] |
| 11. Xulin Lu, Xian-Fu Zhang. (2020) Phosphorous tetrabenzocorrolazine from its metal-free phthalocyanine precursor: Its facile synthesis, high fluorescence emission, efficient singlet oxygen formation, and promising hole transporting material. DYES AND PIGMENTS, 179 (108421). [PMID:] [10.1016/j.dyepig.2020.108421] |
| 12. Fulei Liu, Xiaoxian Huang, Lingfei Han, Mangmang Sang, Lejian Hu, Bowen Liu, Bingjing Duan, Pan Jiang, Xin Wang, Zhou Qiao, Congyu Ma, Wenyuan Liu, Jun Liu, Feng Feng, Wei Qu. (2019) Improved druggability of gambogic acid using core–shell nanoparticles. Biomaterials Science, 7 (3): (1028-1042). [PMID:30608065] [10.1039/C8BM01154K] |
| 13. Lingfei Han, Lejian Hu, Fulei Liu, Xin Wang, Xiaoxian Huang, Bowen Liu, Feng Feng, Wenyuan Liu, Wei Qu. (2019) Redox-sensitive micelles for targeted intracellular delivery and combination chemotherapy of paclitaxel and all-trans-retinoid acid. Asian Journal of Pharmaceutical Sciences, 14 (531). [PMID:32104480] [10.1016/j.ajps.2018.08.009] |
| 14. Mo Zhu, Nairong Hao, Jinxian Yang, Lianwei Li. (2018) A comparative study of intrachain cyclization and solution properties of long-subchain hyperbranched polymers prepared via Y-type and V-type macromonomer approaches. Polymer Chemistry, 9 (20): (2830-2842). [PMID:] [10.1039/C8PY00362A] |
| 15. Bowen Li, Peilian Liu, Hao Wu, Xin Xie, Zelin Chen, Fang Zeng, Shuizhu Wu. (2017) A bioorthogonal nanosystem for imaging and in vivo tumor inhibition. BIOMATERIALS, 138 (57). [PMID:28554008] [10.1016/j.biomaterials.2017.05.036] |
| 16. Bin Jiang, Zhaohe Huang, Luhong Zhang, Yongli Sun, Huawei Yang, Hanrong Bi. (2016) Highly efficient and reversible CO2 capture by imidazolate-based ether-functionalized ionic liquids with a capture transforming process. Journal of the Taiwan Institute of Chemical Engineers, 69 (85). [PMID:] [10.1016/j.jtice.2016.10.009] |
| 17. Keyi Wang, Yingzhuang Chen, Huihui Yang, Yi Li, Lihua Nie, Shouzhuo Yao. (2012) Modification of VTMS hybrid monolith via thiol-ene click chemistry for capillary electrochromatography. TALANTA, 91 (52). [PMID:22365679] [10.1016/j.talanta.2012.01.009] |
| 1. Rahul A Patil,Mohsen Talebi,Alain Berthod,Daniel W Armstrong. (2018-01-31) Dicationic ionic liquid thermal decomposition pathways.. Analytical and bioanalytical chemistry, 410 ((19)): (4645-4655). [PMID:29380017] |
| 2. Jiang Yan,Qinglei Meng,Xiaojun Shen,Bingfeng Chen,Yang Sun,Junfeng Xiang,Huizhen Liu,Buxing Han. (2020-11-08) Selective valorization of lignin to phenol by direct transformation of Csp2-Csp3 and C-O bonds.. Science advances, 6 ((45)): [PMID:33158871] |
| 3. Yayuan Liu, Fuyue Tian, Jing Hu, Nanying Ning, Bing Yu, Ming Tian. (2023) Photochromic Polyurethane Coatings with Cross-Linked Structure and Self-Healing Behavior Based on the FRET Effect. MACROMOLECULAR RAPID COMMUNICATIONS, 44 (13): (2300097). [PMID:37165710] [10.1002/marc.202300097] |
| 4. Yan Zhao, Xinquan Yu, Xiao Liu, Dailiang Zhang, He Li, Hanlin Zhou, Weiheng Kong, Fengli Qu. (2023) ClO– Induced Dual-Excitation Fluorescent Probes Responding to Diverse Testing Modes with Ratio Methodology. ANALYTICAL CHEMISTRY, 95 (18): (7170–7177). [PMID:37114482] [10.1021/acs.analchem.2c05532] |
| 5. Cheng Deng, Hai Yang, Simin Liu, Zhiyong Zhao. (2023) Self-assembly of Dendrimer-DNA amphiphiles and their catalysis as G-quadruplex/hemin DNAzymes. POLYMER, 266 (125621). [PMID:] [10.1016/j.polymer.2022.125621] |
| 6. Ling Yan, Qing-Song Gu, Wen-Li Jiang, Min Tan, Zhi-Ke Tan, Guo-Jiang Mao, Fen Xu, Chun-Yan Li. (2022) Near-Infrared Fluorescent Probe with Large Stokes Shift for Imaging of Hydrogen Sulfide in Tumor-Bearing Mice. ANALYTICAL CHEMISTRY, 94 (14): (5514–5520). [PMID:35360906] [10.1021/acs.analchem.1c04169] |
| 7. Junjun Wang, Yize Zhang, Zhi-Peng Yu, Houshi Huang, Lei Chen, Xiaojiao Zhu, Jie Zhang, Lianke Wang, Jianhua Yu, Hongping Zhou. (2021) Diversified photo-energy conversion based on single-molecule FRET to realize enhanced phototheranostics. Materials Chemistry Frontiers, 5 (23): (8229-8237). [PMID:] [10.1039/D1QM01105G] |
| 8. Yongchao Yao, Yunlong Yu, Xiaohui Wan, Daoping Yan, Ying Chen, Jianbin Luo, G. Julius Vancso, Shiyong Zhang. (2021) Azobenzene-Based Cross-Linked Small-Molecule Vesicles for Precise Oxidative Damage Treatments Featuring Controlled and Prompt Molecular Release. CHEMISTRY OF MATERIALS, 33 (18): (7357–7366). [PMID:] [10.1021/acs.chemmater.1c01860] |
| 9. Tingting Zheng, Yujie Zhu, Anwei Zhu. (2021) Boronic Acid-containing Stimuli-responsive Polymers Modified Nanopores for Label-free Dual-signal-output Detection of Glucose. ELECTROANALYSIS, 34 (2): (326-331). [PMID:] [10.1002/elan.202100268] |
| 10. Yao Zhu, Yue Qi, Xinghua Guo, Meicheng Zhang, Zhimin Jia, Chuanqin Xia, Ning Liu, Chiyao Bai, Lijian Ma, Qin Wang. (2021) A crystalline covalent organic framework embedded with a crystalline supramolecular organic framework for efficient iodine capture. Journal of Materials Chemistry A, 9 (31): (16961-16966). [PMID:] [10.1039/D1TA03879F] |
| 11. Shuifang Mao, Bin Wang, Lin Yue, Wenshui Xia. (2021) Effects of citronellol grafted chitosan oligosaccharide derivatives on regulating anti-inflammatory activity. CARBOHYDRATE POLYMERS, 262 (117972). [PMID:33838788] [10.1016/j.carbpol.2021.117972] |
| 12. Yang Tian, Dong-Ye Zhou, Wen-Li Jiang, Zun-Pan She, Yongfei Li, Chun-Yan Li. (2021) Novel near-infrared fluorescence probe with large Stokes shift for monitoring CCl4-induced toxic hepatitis. TALANTA, 223 (121720). [PMID:33303166] [10.1016/j.talanta.2020.121720] |
| 13. Xulin Lu, Xian-Fu Zhang. (2020) Phosphorous tetrabenzocorrolazine from its metal-free phthalocyanine precursor: Its facile synthesis, high fluorescence emission, efficient singlet oxygen formation, and promising hole transporting material. DYES AND PIGMENTS, 179 (108421). [PMID:] [10.1016/j.dyepig.2020.108421] |
| 14. Fulei Liu, Xiaoxian Huang, Lingfei Han, Mangmang Sang, Lejian Hu, Bowen Liu, Bingjing Duan, Pan Jiang, Xin Wang, Zhou Qiao, Congyu Ma, Wenyuan Liu, Jun Liu, Feng Feng, Wei Qu. (2019) Improved druggability of gambogic acid using core–shell nanoparticles. Biomaterials Science, 7 (3): (1028-1042). [PMID:30608065] [10.1039/C8BM01154K] |
| 15. Lingfei Han, Lejian Hu, Fulei Liu, Xin Wang, Xiaoxian Huang, Bowen Liu, Feng Feng, Wenyuan Liu, Wei Qu. (2019) Redox-sensitive micelles for targeted intracellular delivery and combination chemotherapy of paclitaxel and all-trans-retinoid acid. Asian Journal of Pharmaceutical Sciences, 14 (531). [PMID:32104480] [10.1016/j.ajps.2018.08.009] |
| 16. Mo Zhu, Nairong Hao, Jinxian Yang, Lianwei Li. (2018) A comparative study of intrachain cyclization and solution properties of long-subchain hyperbranched polymers prepared via Y-type and V-type macromonomer approaches. Polymer Chemistry, 9 (20): (2830-2842). [PMID:] [10.1039/C8PY00362A] |
| 17. Bowen Li, Peilian Liu, Hao Wu, Xin Xie, Zelin Chen, Fang Zeng, Shuizhu Wu. (2017) A bioorthogonal nanosystem for imaging and in vivo tumor inhibition. BIOMATERIALS, 138 (57). [PMID:28554008] [10.1016/j.biomaterials.2017.05.036] |
| 18. Bin Jiang, Zhaohe Huang, Luhong Zhang, Yongli Sun, Huawei Yang, Hanrong Bi. (2016) Highly efficient and reversible CO2 capture by imidazolate-based ether-functionalized ionic liquids with a capture transforming process. Journal of the Taiwan Institute of Chemical Engineers, 69 (85). [PMID:] [10.1016/j.jtice.2016.10.009] |
| 19. Keyi Wang, Yingzhuang Chen, Huihui Yang, Yi Li, Lihua Nie, Shouzhuo Yao. (2012) Modification of VTMS hybrid monolith via thiol-ene click chemistry for capillary electrochromatography. TALANTA, 91 (52). [PMID:22365679] [10.1016/j.talanta.2012.01.009] |
