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(Triphenylphosphoranylidene)acetonitrile - >98.0%(HPLC), high purity , CAS No.16640-68-9
Basic Description
Synonyms | J-010276 | C20H16NP | Strophanthidin-D-cymarosid | (Cyanomethyl)triphenylphosphonium- | (Triphenylphosphoranyl)acetonitrile | (Triphenylphosphoranylidene)acetonitrile | Corglycon | Cyanomethyltriphenylphosphonium ylide | Erizimin | T1958 | BCP22527 | CS-W |
Specifications & Purity | ≥98%(HPLC) |
Storage Temp | Argon charged |
Shipped In | Normal |
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Names and Identifiers
Pubchem Sid | 504755816 |
Pubchem Sid Url | https://pubchem.ncbi.nlm.nih.gov/substance/504755816 |
IUPAC Name | 2-(triphenyl-λ5-phosphanylidene)acetonitrile |
INCHI | InChI=1S/C20H16NP/c21-16-17-22(18-10-4-1-5-11-18,19-12-6-2-7-13-19)20-14-8-3-9-15-20/h1-15,17H |
InChi Key | APISVOVOJVZIBA-UHFFFAOYSA-N |
Canonical SMILES | C1=CC=C(C=C1)P(=CC#N)(C2=CC=CC=C2)C3=CC=CC=C3 |
Isomeric SMILES | C1=CC=C(C=C1)P(=CC#N)(C2=CC=CC=C2)C3=CC=CC=C3 |
WGK Germany | 3 |
PubChem CID | 85524 |
Molecular Weight | 301.33 |
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Certificates(CoA,COO,BSE/TSE and Analysis Chart)
Safety and Hazards(GHS)
Pictogram(s) | GHS07 |
Signal | Warning |
Hazard Statements | H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation |
Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell. |
WGK Germany | 3 |
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References
1. Hiroaki Ohno, Tsuyoshi Mizutani, Yoichi Kadoh, Akimasa Aso, Kumiko Miyamura, Nobutaka Fujii, Tetsuaki Tanaka,. (2007-05-11) A highly regio- and stereoselective formation of bicyclo[4.2.0]oct-5-ene derivatives through thermal intramolecular [2 + 2] cycloaddition of allenes.. The Journal of organic chemistry, 72 ((12)): ( 4378-4389 ). [PMID:17489635] |
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