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Basic Description
| Synonyms | DIIDOTRIPHENYLPHOSPHORANE | I2-PPh3 | AC9088 | AKOS015916033 | 4-16-00-01013 (Beilstein Handbook Reference) | Iodotriphenylphosphoranium iodide | Phosphorane, diiodotriphenyl- | BRN 2740417 | Diiodotriphenylphosphorane | diiodo(triphenyl)-lambda5-phosphan |
|---|---|
| Specifications & Purity | ≥88% |
| Storage Temp | Protected from light,Room temperature |
| Shipped In | Normal |
| Product Description | Application： Triphenylphosphine diiodide (Ph3P. I2) can be used as a reagent: To facilitate the conversion of alcohol, thiol, and enol functional groups into alkyl iodides via formation of alkoxyphosphonium iodide. To prepare β-iodo-α,β-unsaturated ketones from cyclic β-diketones in the presence of triethyl amine. In the synthesis of alkyl nitrates from alcohols. In the Beckmann rearrangement reaction to synthesize lactams from cycloalkanone oxime. For the preparation of aromatic and aliphatic carboxylic acid esters in the presence of N,N-dimethylaminopyridine. Ph3P. I2 can also be used to reduce graphene oxide for the production of graphene nanosheets under mild and environmentally friendly conditions. |
AI Insight
Names and Identifiers
| Pubchem Sid | 488188611 |
|---|---|
| IUPAC Name | diiodo(triphenyl)-λ5-phosphane |
| INCHI | InChI=1S/C18H15I2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H |
| InChi Key | NSWZEXJQHIXCFL-UHFFFAOYSA-N |
| Canonical SMILES | C1=CC=C(C=C1)P(C2=CC=CC=C2)(C3=CC=CC=C3)(I)I |
| Isomeric SMILES | C1=CC=C(C=C1)P(C2=CC=CC=C2)(C3=CC=CC=C3)(I)I |
| PubChem CID | 201622 |
| UN Number | 2923 |
| Packing Group | II |
| Molecular Weight | 516.09 |
Certificates（CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:
Find and download the COA for your product by matching the lot number on the packaging.
| Lot Number | Certificate Type | Date | Item |
|---|---|---|---|
 C2506059 | Certificate of Analysis | Mar 04, 2023 | T331414 |
| D23011136 | Certificate of Analysis | Mar 04, 2023 | T331414 |
| D23011137 | Certificate of Analysis | Mar 04, 2023 | T331414 |
| D23011138 | Certificate of Analysis | Mar 04, 2023 | T331414 |
| D23011144 | Certificate of Analysis | Mar 04, 2023 | T331414 |
| D23011145 | Certificate of Analysis | Mar 04, 2023 | T331414 |
| D23011146 | Certificate of Analysis | Mar 04, 2023 | T331414 |
Safety and Hazards(GHS)
| Pictogram(s) | GHS08, GHS05 |
|---|---|
| Signal | Danger |
| Hazard Statements | H314:Causes severe skin burns and eye damage H317:May cause an allergic skin reaction H334:May cause allergy or asthma symptoms or breathing difficulties if inhaled H361:Suspected of damaging fertility or the unborn child |
| Precautionary Statements | P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P202:Do not handle until all safety precautions have been read and understood. |
| Class | 8 (6.1) |