Trifluoroacetic acid-d - 99.5 atom % D+0.03%TMS,for NMR, high purity , CAS No.599-00-8

  • ≥99.5 atom% D
  • contains 0.03%(v/v) TMS,for NMR
Item Number
T109782
Grouped product items
SKUSizeAvailabilityPrice Qty
T109782-5g
5g
3
$103.90
T109782-10g
10g
3
$171.90
T109782-25g
25g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$399.90

Basic Description

SynonymsTrifluoroacetic acid-d | 599-00-8 | deuterio 2,2,2-trifluoroacetate | Deuterotrifluoroacetic acid | TFA-d | CF3COOD | Acetic acid-d, trifluoro- | deuterated trifluoroacetic acid | MFCD00044563 | Trifluoroacetic acid-d (TFA-d) | Trifluoroacetic acid-d, 99.5 atom % D | Acetic ac
Specifications & Purity≥99.5 atom% D, contains 0.03%(v/v) TMS,for NMR
Storage TempArgon charged
Shipped InNormal
Product Description

Trifluoroacetic acid-d is a standard purity solvent suitable for routine NMR analyses (conducted at ambient temperatures where quality is less critical).
Trifluoroacetic acid-d is a synthetic reagent having isotopic purity of 99.5atom%D. It undergoes SE′ reaction with (R)-(E)-1,3-diphenyl-3-trimethylsilylpropene, via antistereochemistry to afford (R)-(E)-1,3-diphenylpropene-3-d.Vapor phase dissociation of trifluoroacetic acid-d has been studied.
Application:

Trifluoroacetic acid-d may be employed as solvent to investigate the conformations of cyclic peptides by proton NMR spectra. It may be used to compose NMR solvent mixture to investigate the NMR spectra of high molecular weight polyesters such as polyglycolide (PG) and poly(ethylene terephthalate) (PET).

AI Insight

Names and Identifiers

IUPAC Name deuterio 2,2,2-trifluoroacetate
INCHI InChI=1S/C2HF3O2/c3-2(4,5)1(6)7/h(H,6,7)/i/hD
InChi Key DTQVDTLACAAQTR-DYCDLGHISA-N
Canonical SMILES C(=O)(C(F)(F)F)O
Isomeric SMILES [2H]OC(=O)C(F)(F)F
WGK Germany 3
PubChem CID 71502
UN Number 2699
Molecular Weight 115.03
Beilstein 1768662

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

15 results found

Lot NumberCertificate TypeDateItem
H2103397Certificate of AnalysisDec 12, 2024 T109782
G1804155Certificate of AnalysisDec 12, 2024 T109782
B2309819Certificate of AnalysisNov 04, 2024 T109782
J2409514Certificate of AnalysisSep 06, 2024 T109782
J2409515Certificate of AnalysisSep 06, 2024 T109782
C2419361Certificate of AnalysisMar 07, 2024 T109782
H2103464Certificate of AnalysisJan 02, 2024 T109782
A2220325Certificate of AnalysisOct 16, 2023 T109782
A2220346Certificate of AnalysisOct 16, 2023 T109782
I2305682Certificate of AnalysisAug 26, 2023 T109782
I2305683Certificate of AnalysisAug 26, 2023 T109782
I2305685Certificate of AnalysisAug 26, 2023 T109782
B2309883Certificate of AnalysisNov 05, 2022 T109782
B2309890Certificate of AnalysisNov 05, 2022 T109782
A2220344Certificate of AnalysisDec 29, 2021 T109782

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Safety and Hazards(GHS)

Pictogram(s) GHS05,   GHS07
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

H412:Harmful to aquatic life with long lasting effects

H332:Harmful if inhaled

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P271:Use only outdoors or in a well-ventilated area.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P317:Get emergency medical help.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

WGK Germany 3

Related Documents

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Customer Reviews

Citations of This Product

1. Qian Zhang, Ying Li, Shuai Wang, Donghao Gu, Cuihua Zhang, Shihao Xu, Xiaoli Fang, Chenyang Li, Haiqiang Wu, Wei Xiong.  (2024)  Chitosan-based oral nanoparticles as an efficient platform for kidney-targeted drug delivery in the treatment of renal fibrosis.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,  256  (128315).  [PMID:38000609] [10.1016/j.ijbiomac.2023.128315]
2. Xiong Zheng, Qiang Shi, Xuzhen Zhang, Wenjian Huang, Zhou Zhang, Bona Ding.  (2023)  The role and mechanism of temporary blocked isocyanate at interface between polyethylene terephthalate high-strength fibers and activation oil.  JOURNAL OF APPLIED POLYMER SCIENCE,    (e54992).  [PMID:] [10.1002/app.54992]
3. Shikun Zhao, Shun Gong, Biao Zhao, Like Hou, Lurong Zhang, Qing Hu, Kai Pan.  (2023)  Mechanism Study of the Polymerization of Polyamide 56: Reaction Kinetics and Process Parameters.  MACROMOLECULAR RAPID COMMUNICATIONS,  44  (24): (2300371).  [PMID:37657922] [10.1002/marc.202300371]
4. Diansong Gan, Yuejun Liu, Tianhui Hu, Shuhong Fan, Xiaochao Liu, Lingna Cui, Ling Yang, Yincai Wu, Lily Chen, Zhixiang Mo.  (2023)  The Investigation of Copolymer Composition Sequence on Non-Isothermal Crystallization Kinetics of Bio-Based Polyamide 56/512.  Polymers,  15  (10): (2345).  [PMID:37242922] [10.3390/polym15102345]
5. Shuhan Hou, Inseob Noh, Xinlu Shi, Yanbin Wang, Hyung Do Kim, Hideo Ohkita, Biaobing Wang.  (2023)  Facile fabrication of flexible superhydrophobic surfaces with high durability and good mechanical strength through embedding silica nanoparticle into polymer substrate by spraying method.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,  664  (131181).  [PMID:] [10.1016/j.colsurfa.2023.131181]
6. Xinran Liu, Yu Wang, Yongyan Pang, Xia Dong, Dujin Wang.  (2022)  A rheological method to characterize the molecular weight changes of polyamide 1012 during solid state polymerization.  JOURNAL OF APPLIED POLYMER SCIENCE,  139  (45): (e53131).  [PMID:] [10.1002/app.53131]
7. Xin Tong, Zhao Wang, Mei-Ling Zhang, Xiao-Jun Wang, Gang Zhang, Sheng-Ru Long, Jie Yang.  (2021)  Synthesis, Characterization and Non-Isothermal Crystallization Kinetics of a New Family of Poly (Ether-Block-Amide)s Based on Nylon 10T/10I.  Polymers,  13  (1): (72).  [PMID:33375409] [10.3390/polym13010072]
8. Tao Lei, Liu Ke, Li Taotao, Xiao Ru.  (2020)  Preparation and properties of biobased polyamides based on 1,9-azelaic acid and different chain length diamines.  POLYMER BULLETIN,  77  (3): (1135-1156).  [PMID:] [10.1007/s00289-019-02791-2]
9. Xiansong Wang, Qingyin Wang, Shaoying Liu, Gongying Wang.  (2018)  Biobased copolyesters: Synthesis, structure, thermal and mechanical properties of poly(ethylene 2,5-furandicarboxylate-co-ethylene 1,4-cyclohexanedicarboxylate).  POLYMER DEGRADATION AND STABILITY,  154  (96).  [PMID:] [10.1016/j.polymdegradstab.2018.05.026]
10. Chan Feng, Kun Wang, Yun Lin, Zhiwang Song, Yonglin Lu, Jie Liu, Donglei Zhu, Yongyong Li, Chunyan Dong.  (2018)  Extracellular retention of a cyclopamine nanoformulation leveraging larger size and more negative charge for improved breast cancer treatment.  Journal of Materials Chemistry B,  (12): (1834-1843).  [PMID:32254255] [10.1039/C7TB02777J]
11. Lingzhi Zhao, Zhao Li, Liu Zhao, Chenxiao Zhang.  (2017)  In Vivo Determination of Reduced Thiols in Rat Cerebellum Paraflocculus Following Salicylate-Induced Tinnitus by Fluorescence.  ANALYTICAL LETTERS,      [PMID:] [10.1080/00032719.2016.1186170]

References

1. Qian Zhang, Ying Li, Shuai Wang, Donghao Gu, Cuihua Zhang, Shihao Xu, Xiaoli Fang, Chenyang Li, Haiqiang Wu, Wei Xiong.  (2024)  Chitosan-based oral nanoparticles as an efficient platform for kidney-targeted drug delivery in the treatment of renal fibrosis.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,  256  (128315).  [PMID:38000609] [10.1016/j.ijbiomac.2023.128315]
2. Xiong Zheng, Qiang Shi, Xuzhen Zhang, Wenjian Huang, Zhou Zhang, Bona Ding.  (2023)  The role and mechanism of temporary blocked isocyanate at interface between polyethylene terephthalate high-strength fibers and activation oil.  JOURNAL OF APPLIED POLYMER SCIENCE,    (e54992).  [PMID:] [10.1002/app.54992]
3. Shikun Zhao, Shun Gong, Biao Zhao, Like Hou, Lurong Zhang, Qing Hu, Kai Pan.  (2023)  Mechanism Study of the Polymerization of Polyamide 56: Reaction Kinetics and Process Parameters.  MACROMOLECULAR RAPID COMMUNICATIONS,  44  (24): (2300371).  [PMID:37657922] [10.1002/marc.202300371]
4. Diansong Gan, Yuejun Liu, Tianhui Hu, Shuhong Fan, Xiaochao Liu, Lingna Cui, Ling Yang, Yincai Wu, Lily Chen, Zhixiang Mo.  (2023)  The Investigation of Copolymer Composition Sequence on Non-Isothermal Crystallization Kinetics of Bio-Based Polyamide 56/512.  Polymers,  15  (10): (2345).  [PMID:37242922] [10.3390/polym15102345]
5. Shuhan Hou, Inseob Noh, Xinlu Shi, Yanbin Wang, Hyung Do Kim, Hideo Ohkita, Biaobing Wang.  (2023)  Facile fabrication of flexible superhydrophobic surfaces with high durability and good mechanical strength through embedding silica nanoparticle into polymer substrate by spraying method.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,  664  (131181).  [PMID:] [10.1016/j.colsurfa.2023.131181]
6. Xinran Liu, Yu Wang, Yongyan Pang, Xia Dong, Dujin Wang.  (2022)  A rheological method to characterize the molecular weight changes of polyamide 1012 during solid state polymerization.  JOURNAL OF APPLIED POLYMER SCIENCE,  139  (45): (e53131).  [PMID:] [10.1002/app.53131]
7. Xin Tong, Zhao Wang, Mei-Ling Zhang, Xiao-Jun Wang, Gang Zhang, Sheng-Ru Long, Jie Yang.  (2021)  Synthesis, Characterization and Non-Isothermal Crystallization Kinetics of a New Family of Poly (Ether-Block-Amide)s Based on Nylon 10T/10I.  Polymers,  13  (1): (72).  [PMID:33375409] [10.3390/polym13010072]
8. Tao Lei, Liu Ke, Li Taotao, Xiao Ru.  (2020)  Preparation and properties of biobased polyamides based on 1,9-azelaic acid and different chain length diamines.  POLYMER BULLETIN,  77  (3): (1135-1156).  [PMID:] [10.1007/s00289-019-02791-2]
9. Xiansong Wang, Qingyin Wang, Shaoying Liu, Gongying Wang.  (2018)  Biobased copolyesters: Synthesis, structure, thermal and mechanical properties of poly(ethylene 2,5-furandicarboxylate-co-ethylene 1,4-cyclohexanedicarboxylate).  POLYMER DEGRADATION AND STABILITY,  154  (96).  [PMID:] [10.1016/j.polymdegradstab.2018.05.026]
10. Chan Feng, Kun Wang, Yun Lin, Zhiwang Song, Yonglin Lu, Jie Liu, Donglei Zhu, Yongyong Li, Chunyan Dong.  (2018)  Extracellular retention of a cyclopamine nanoformulation leveraging larger size and more negative charge for improved breast cancer treatment.  Journal of Materials Chemistry B,  (12): (1834-1843).  [PMID:32254255] [10.1039/C7TB02777J]
11. Lingzhi Zhao, Zhao Li, Liu Zhao, Chenxiao Zhang.  (2017)  In Vivo Determination of Reduced Thiols in Rat Cerebellum Paraflocculus Following Salicylate-Induced Tinnitus by Fluorescence.  ANALYTICAL LETTERS,      [PMID:] [10.1080/00032719.2016.1186170]

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