| SKU | Size | Availability | Price | Qty |
|---|---|---|---|---|
| T140663-25ml | 25ml | Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding. | $288.90 |
| Synonyms | TBB |
|---|---|
| Specifications & Purity | 1.0 M in THF |
| Storage Temp | Store at 2-8°C,Argon charged |
| Shipped In | Wet ice |
| Product Description | Reactant for: · Addition reactions for synthesis of phenyltrialkylborate salts. · Boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines. · Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists. · Multicomponent C-alkylation reactions with aromatic aldimines. · One-pot alkylation-boration and electrophilic substitution. Application： Tri-n-butylborane is used as a reactant for addition reactions for synthesis of phenyltrialkylborate salts, boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines, Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists, multicomponent C-alkylation reactions with aromatic aldimines, one-pot alkylation-boration and electrophilic substitution. |
| UN Number | 1993 |
|---|---|
| Packing Group | II |
| Molecular Weight | 182.15 |
| Solubility | Not miscible or difficult to mix with water. |
|---|---|
| Sensitivity | air sensitive. Moisture Sensitive |
| Pictogram(s) | GHS08, GHS05, GHS07, GHS02 |
|---|---|
| Signal | Danger |
| Hazard Statements | H335:May cause respiratory irritation H351:Suspected of causing cancer H314:Causes severe skin burns and eye damage H302:Harmful if swallowed H225:Highly Flammable liquid and vapor H336:May cause drowsiness or dizziness |
| Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P405:Store locked up. P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P403+P235:Store in a well-ventilated place. Keep cool. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P201:Obtain special instructions before use. P308+P313:IF exposed or concerned: Get medical advice/attention. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P270:Do not eat, drink or smoke when using this product. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363:Wash contaminated clothing before reuse. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P202:Do not handle until all safety precautions have been read and understood. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P301+P312+P330:IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. |
| 1. Atsushi Kameyama,Soichiro Ihara,Tetsuya Amagai,Yasuo Miake,Eiji Kawada,Yutaka Oda,Takaaki Yanagisawa,Yoshito Hirai. (2003-06-07) Adhesion of 4-META/MMA-TBB resin to heated dentin: effects of pre-treatments with FeCl3 and/or HEMA.. Dental materials journal, 22 ((1)): (1-9). [PMID:12790291] |
| 2. Chiemi Hirabayashi. (2003-06-07) Studies on MMA-TBB resin II. The effect of dual use of TBB and other initiators on polymerization of PMMA/MMA resin.. Dental materials journal, 22 ((1)): (48-55). [PMID:12790296] |
| 3. Yohsuke Taira,Hideo Matsumura,Mitsuru Atsuta. (2003-06-17) Bonded interface between a self-curing resin and dentin primed with a metalloprotein.. Journal of biomedical materials research. Part B, Applied biomaterials, 66 ((1)): (414-418). [PMID:12808602] |
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| 5. Seiichiro Fujisawa,Toshiko Atsumi. (2004-08-04) Cytotoxicities of a 4-META/MMA-TBBO resin against human pulp fibroblasts.. Dental materials journal, 23 ((2)): (106-108). [PMID:15287554] |
| 6. Tae-Yub Kwon,Yohji Imai. (2004-08-04) Polymerization characteristics of ethyl methacrylate-based resin initiated by TBB.. Dental materials journal, 23 ((2)): (161-165). [PMID:15287562] |
| 7. Naomi Tanoue,Yoshikazu Koishi,Hiroaki Yanagida,Mitsuru Atsuta,Kazuki Shimada,Hideo Matsumura. (2004-10-30) Color stability of acrylic resin adhesives with different initiation modes.. Dental materials journal, 23 ((3)): (368-372). [PMID:15510867] |
| 8. Kiyoshi Nagano,Naomi Tanoue,Mitsuru Atsuta,Hiroyasu Koizumi,Hideo Matsumura. (2005-05-20) Effect of noble metal adhesive systems on bonding between an indirect composite material and a gold alloy.. Journal of oral science, 46 ((4)): (235-239). [PMID:15901068] |
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| 11. Yohsuke Taira,Kohyoh Soeno,Mitsuru Atsuta. (2006-08-31) Microperoxidase primer promotes adhesion of butylborane-polymerized resin to dentin.. Journal of biomedical materials research. Part B, Applied biomaterials, 81 ((1)): (111-115). [PMID:16941583] |
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| 15. Takaya Ishii,Hiroyasu Koizumi,Takayuki Yoneyama,Naomi Tanoue,Yumi Ishikawa,Hideo Matsumura. (2008-03-04) Comparative evaluation of thione and phosphate monomers on bonding gold alloy and Ti-6Al-7Nb alloy with tri-n-butylborane initiated resin.. Dental materials journal, 27 ((1)): (56-60). [PMID:18309612] |
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