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Tetrakis(triphenylphosphine)palladium(0) - 99%, high purity , CAS No.14221-01-3

107 Citations
  • ≥99%
Item Number
T359229
Grouped product items
SKUSizeAvailabilityPrice Qty
T359229-1g
1g
5
$42.90
T359229-5g
5g
2
$169.90
T359229-25g
25g
1
$599.90
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Cross-couplling catalysts (4) Palladium catalyst (74)

Basic Description

Synonymstetrakis(triphenylphosphine)-palladium(0) | Pd(PPh3)4
Specifications & Purity≥99%
Storage TempProtected from light,Store at -20°C,Argon charged
Shipped InIce chest + Ice pads
Product Description

A high-yielding catalyst used in coupling reactions.

Product class

M-P, Homogeneous Catalysts, Monodentate Ligands, Phosphorus Ligands - Achiral


Reaction type

Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Carbonylation, Hiyama Coupling Reaction, Mizoroki Heck Coupling Reaction, Negishi Coupling Reaction, Sonogashira-Hagihara Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Cyclization, Isomerization, Oxidation, Reduction


Chemical properties

Chemical formula

C72H60P4Pd

Empirical formula

[Pd(PPh3)4]

Molecular weight

1155.58

Metal

Pd

Theoretical metal content

9

Physical state

crystalline

Color

yellow

Applications & references

Suzuki coupling reaction as key synthesis step in the preparation of the chiral, nonracemic 3-aryl piperidine (OSU 6162), a potential central nervous system agent.


Reference: Org. Proc. Res. Dev. 2003, 7, 385. (DOI: 10.1021/op025620u)


Aryl-aryl Negishi coupling reaction in the preparation of 5-[2-Methoxy-5-(4-pyridinyl)phenyl]-2,1,3-benzoxadiazole (PDE472), a selective inhibitor of the phosphodiesterase PDE4D isoenzyme, which is well known as drug target for the treatment of asthma.


Reference: Org. Proc. Res. Dev. 2003, 7, 436. (DOI: 10.1021/op025615q)

Palladium catalyzed synthesis of trans-1,2-diazetidines by cyclization of 2,3-allenyl hydrazines with aryl halides.

Reference: Angew. Chem. Int. Ed. 2008, 47, 4581. (DOI: 10.1021/anie.200800364)

Palladium catalyzed cross coupling reaction of α-diazocarbonyl compounds with arylboronic acids providing access to α-aryl substituted α,β-unsaturated carbonyl compounds.

Reference: J. Am. Chem. Soc. 2008, 130, 1566. (DOI: 10.1021/ja0782293)

Palladium catalyzed intermolecular decarboxylative coupling in the presence of reactive C-H groups.

Reference: J. Org. Chem. 2010, 75, 1550. (DOI: 10.1021/jo9022793)

AI Insight

Names and Identifiers

Pubchem Sid504766857
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/504766857
IUPAC Name palladium;triphenylphosphane
INCHI InChI=1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
InChi Key NFHFRUOZVGFOOS-UHFFFAOYSA-N
Canonical SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Pd]
Isomeric SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Pd]
WGK Germany 3
PubChem CID 11979704
Molecular Weight 1155.56
Beilstein 6704828
Reaxy-Rn 6704828

Certificates（CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

33 results found

Lot NumberCertificate TypeDateItem
G2310160Certificate of AnalysisApr 09, 2025 T359229
G2310159Certificate of AnalysisApr 09, 2025 T359229
A2516359Certificate of AnalysisJan 03, 2025 T359229
A2516362Certificate of AnalysisJan 03, 2025 T359229
A2516357Certificate of AnalysisJan 03, 2025 T359229
B2301731Certificate of AnalysisNov 08, 2024 T359229
K2414432Certificate of AnalysisOct 21, 2024 T359229
K2414475Certificate of AnalysisOct 21, 2024 T359229
K2414478Certificate of AnalysisOct 21, 2024 T359229
H2413622Certificate of AnalysisJul 08, 2024 T359229
H2413621Certificate of AnalysisJul 08, 2024 T359229
H2413620Certificate of AnalysisJul 08, 2024 T359229
D2430133Certificate of AnalysisApr 13, 2024 T359229
D2430132Certificate of AnalysisApr 13, 2024 T359229
D2430131Certificate of AnalysisApr 13, 2024 T359229
C2419477Certificate of AnalysisMar 09, 2024 T359229
C2419476Certificate of AnalysisMar 09, 2024 T359229
C2419475Certificate of AnalysisMar 09, 2024 T359229
L2318462Certificate of AnalysisDec 07, 2023 T359229
L2318463Certificate of AnalysisDec 07, 2023 T359229
L2318464Certificate of AnalysisDec 07, 2023 T359229
K2302101Certificate of AnalysisJun 15, 2023 T359229
G2310163Certificate of AnalysisJun 15, 2023 T359229
G2310161Certificate of AnalysisJun 15, 2023 T359229
B2301728Certificate of AnalysisDec 08, 2022 T359229
B2301725Certificate of AnalysisDec 08, 2022 T359229
B23011031Certificate of AnalysisDec 08, 2022 T359229
I2222343Certificate of AnalysisSep 05, 2022 T359229
I2222346Certificate of AnalysisSep 05, 2022 T359229
I2222347Certificate of AnalysisSep 05, 2022 T359229
K2207089Certificate of AnalysisSep 05, 2022 T359229
K2229702Certificate of AnalysisSep 05, 2022 T359229
F2309019Certificate of AnalysisSep 05, 2022 T359229

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Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H413:May cause long lasting harmful effects to aquatic life

H302:Harmful if swallowed

H317:May cause an allergic skin reaction

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P270:Do not eat, drink or smoke when using this product.

P272:Contaminated work clothing should not be allowed out of the workplace.

P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P301+P317:IF SWALLOWED: Get medical help.

WGK Germany 3
Reaxy-Rn 6704828

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