Mercury(II) bromide - ACS reagent, high purity , CAS No.7789-47-1

Item Number
M475241
Grouped product items
SKUSizeAvailabilityPrice Qty
M475241-25g
25g
4
$39.90
M475241-100g
100g
1
$124.90

Basic Description

Synonymsbromure mercurique | UNII-P986675T8V | mercury(2+);dibromide | MERCURIC BROMIDE | Mercury dibromide | EINECS 232-169-3 | Mercuric dibromide | DIBROMOMERCURY | HgBr2 | HSDB 829 | Mercury(2)bromide | Mercury(II) bromide | Mercury bromide (HgBr2)
Specifications & PurityACS
Storage TempProtected from light,Room temperature
Shipped InNormal
GradeACS
Product Description

Mercury(II) bromide (HgBr2) affords 1:1 adducts on reaction withN,N,N′,N′- tetramethyl-o-phenylenediamine. Single-crystal X-ray diffraction studies of these adducts have been reported. It forms complexes by reacting with 3,12-dimethylbenzo[a]quinoxalino[2,3-c]phenazine ligand.Mercury(II) bromide (HgBr2) may be used in the preparation of mononuclear [Hg(L1)Br2] and 1D polymer [Hg2(L2)Br4]n[L1 = (N,N-diethyl,N′-(pyridin-2-yl)formylidene)ethane-1,2-diamine and L2 = (N,N-diethyl,N′-(pyridin-2-yl)benzylidene)ethane-1,2-diamine]. It may also be used as a promoter in the glycoslyation reaction of alcohols.


Application:

Mercury(II) bromide is used as a reagent in the Koenigs-Knorr reaction, which forms glycoside linkages on carbohydrates. It is also used to test for the presence of arsenic, as recommended by the Pharmacopoeia.

AI Insight

Names and Identifiers

Pubchem Sid488182908
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488182908
IUPAC Name dibromomercury
INCHI InChI=1S/2BrH.Hg/h2*1H;/q;;+2/p-2
InChi Key NGYIMTKLQULBOO-UHFFFAOYSA-L
Canonical SMILES Br[Hg]Br
Isomeric SMILES Br[Hg]Br
WGK Germany 3
RTECS OV7415000
PubChem CID 24612
UN Number 1634
Packing Group II
Molecular Weight 360.4

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

13 results found

Lot NumberCertificate TypeDateItem
K2405453Certificate of AnalysisOct 18, 2024 M475241
K2405454Certificate of AnalysisOct 18, 2024 M475241
E2423567Certificate of AnalysisMay 14, 2024 M475241
E2423568Certificate of AnalysisMay 14, 2024 M475241
J2409096Certificate of AnalysisMay 14, 2024 M475241
B2423246Certificate of AnalysisJan 15, 2024 M475241
B2423247Certificate of AnalysisJan 15, 2024 M475241
B2423251Certificate of AnalysisJan 15, 2024 M475241
B2423252Certificate of AnalysisJan 15, 2024 M475241
F2320309Certificate of AnalysisJun 09, 2023 M475241
F2320316Certificate of AnalysisJun 09, 2023 M475241
F2320321Certificate of AnalysisJun 09, 2023 M475241
F2320322Certificate of AnalysisJun 09, 2023 M475241

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Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS08,   GHS09,   GHS05
Signal Danger
Hazard Statements

H315:Causes skin irritation

H373:Causes damage to organs through prolonged or repeated exposure

H318:Causes serious eye damage

H317:May cause an allergic skin reaction

H410:Very toxic to aquatic life with long lasting effects

H300+H310+H330:Fatal if swallowed, in contact with skin or if inhaled

Precautionary Statements

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P310:Immediately call a POISON CENTER or doctor/physician.

P302+P352:IF ON SKIN: wash with plenty of water.

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P361:Take off immediately all contaminated clothing.

P330:Rinse mouth.

P262:Do not get in eyes, on skin, or on clothing.

WGK Germany 3
RTECS OV7415000
Class 6.1

Related Documents

Reviews

Customer Reviews

References

1. G Medgyes,G Jerkovich,J Kuszmann,P Fügedi.  (1989-03-15)  Synthesis of sorbistin analogues..  Carbohydrate research,  186  ((2)): (225-239).  [PMID:2736560]
2. T Endo,S Nakaya,R Kimura.  (1990-05-01)  Mechanisms of absorption of inorganic mercury from rat small intestine. III. Comparative absorption studies of inorganic mercuric compounds in vitro..  Pharmacology & toxicology,  66  ((5)): (347-353).  [PMID:2371240]
3. S Engst,S M Miller.  (1998-08-26)  Rapid reduction of Hg(II) by mercuric ion reductase does not require the conserved C-terminal cysteine pair using HgBr2 as the substrate..  Biochemistry,  37  ((33)): (11496-11507).  [PMID:9708985]
4. A Tobari,T Shimizu,H Miyamae,A Nagasawa,M Kawase,S Saito.  (1998-11-20)  Cyanoglycosylation products of 17-O-acetyl-testosterone..  Carbohydrate research,  310  ((4)): (239-252).  [PMID:9821262]
5. Olivier Gueldry,Myriam Lazard,Florence Delort,Marc Dauplais,Ioana Grigoras,Sylvain Blanquet,Pierre Plateau.  (2003-05-21)  Ycf1p-dependent Hg(II) detoxification in Saccharomyces cerevisiae..  European journal of biochemistry,  270  ((11)): (2486-2496).  [PMID:12755704]
6. M E Goodsite,J M C Plane,H Skov.  (2004-04-13)  A theoretical study of the oxidation of Hg0 to HgBr2 in the troposphere..  Environmental science & technology,  38  ((6)): (1772-1776).  [PMID:15074688]
7. Don S Forsyth,V Casey,R W Dabeka,A McKenzie.  (2005-01-26)  Methylmercury levels in predatory fish species marketed in Canada..  Food additives and contaminants,  21  ((9)): (849-856).  [PMID:15666978]
8. G Ahmed,Alpa Dashora,M Sharma,B L Ahuja.  (2009-12-04)  Compton profiles and electronic structure of HgBr(2) and HgI(2)..  Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine,  68  ((2)): (286-292).  [PMID:19954993]
9. Rui Yang,Jian Ping Ma,Ru Qi Huang,Yu Bin Dong.  (2011-06-03)  Coordination-directed one-dimensional coordination polymers generated from a new oxadiazole bridging ligand and HgX2 (X=Cl, Br and I)..  Acta crystallographica. Section C, Crystal structure communications,  67  ((Pt 6)): (m176-m180).  [PMID:21633149]
10. L G Tereshchenko.  (1984-06-01)  [Potential hazard of the effect of halogen derivatives of inorganic mercury on the body]..  Vrachebnoe delo,  (6)  ((6)): (111-113).  [PMID:6236612]

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