| SKU | Size | Availability | Price | Qty |
|---|---|---|---|---|
| K466838-250mg | 250mg | Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding. | $670.90 |
| Synonyms | Ru(4,4-dicarboxylic acid-2,2 inverted exclamation marka-bipyridine)(4,4 inverted exclamation marka-bis(p-hexyloxystyryl)-2,2-bipyridine)(NCS)2 | starbld0035007 | F75014 | Ru(4,4-dicarboxylic acid-2,2'-bipyridine)(4,4'-bis(p-hexyloxystyryl)-2,2-bipyridine) |
|---|---|
| Specifications & Purity | ≥85%(HPLC) |
| Legal Information | Dyesol®Product. Dyesol is a registered trademark of Dyesol Ltd.Dyesol is a registered trademark of Greatcell Solar |
| Product Description | Description K19 Dye is an amphiphilic ruthenium sensitizer with a good molar extinction coefficient, which remains stable under thermal stress and light soaking. It can be synthesized by forming a reaction mixture of 4,4′-Bis(p-hexyloxystyryl)-2,2′-bipyridine, dichloro(p-cymene)ruthenium(II) dimer, and 4,4′-dicarboxylic acid-2,2′-bipyridine. It shows an overall power conversion efficiency (PCE) of 11% and can be used as an active material in electrochemical applications.K19 Dye is an organo-metallic dye that can be used as a photosensitizing material in the fabrication of dye sensitized solar cells (DSSCs). It shows a short circuit photocurrent density of 15.1 mA/cm2, an open circuit voltage of 747 mV and a fill factor of 0.69.Electron transfer from K-19 dye to the conduction band of Titania is completed within 20 fs while charge recombination has a half-life of 800 μs. The high extinction coefficient of this sensitizer enable realization of a new generation thin-film dye-sensitized solar cells (DSCs) yielding high conversion efficiency at full sunlight, even with viscous electrolytes based on ionic liqs. or nonvolatile solvents, making solar cell devices exhibit excellent stability under light soaking. |
| INCHI | InChI=1S/C38H44N2O2.C12H8N2O4.2CNS.Ru/c1-3-5-7-9-27-41-35-19-15-31(16-20-35)11-13-33-23-25-39-37(29-33)38-30-34(24-26-40-38)14-12-32-17-21-36(22-18-32)42-28-10-8-6-4-2;15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h11-26,29-30H,3-10,27-28H2,1-2H3;1-6H,(H,15,16)(H,17,18);;;/q;;2*-1;+2/b13-11+,14-12+;;;; |
|---|---|
| InChi Key | HBARXZGSEMEPLK-BPSJQPAOSA-N |
| Canonical SMILES | CCCCCCOC1=CC=C(C=C1)C=CC2=CC(=NC=C2)C3=NC=CC(=C3)C=CC4=CC=C(C=C4)OCCCCCC.C1=CN=C(C=C1C(=O)O)C2=NC=CC(=C2)C(=O)O.C(=[N-])=S.C(=[N-])=S.[Ru+2] |
| Isomeric SMILES | CCCCCCOC1=CC=C(C=C1)/C=C/C2=CC(=NC=C2)C3=NC=CC(=C3)/C=C/C4=CC=C(C=C4)OCCCCCC.C1=CN=C(C=C1C(=O)O)C2=NC=CC(=C2)C(=O)O.C(=S)=[N-].C(=S)=[N-].[Ru+2] |
| PubChem CID | 155905579 |
| Molecular Weight | 1,022.21 g/mol |
| Pictogram(s) | GHS07 |
|---|---|
| Signal | Warning |
| Hazard Statements | H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H317:May cause an allergic skin reaction |
| Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell. |
| RIDADR | NONH for all modes of transport |
| 1. Peng Wang,Cédric Klein,Robin Humphry-Baker,Shaik M Zakeeruddin,Michael Grätzel. (2005-01-20) A high molar extinction coefficient sensitizer for stable dye-sensitized solar cells.. Journal of the American Chemical Society, 127 ((3)): (808-809). [PMID:15656598] |
| 2. Daibin Kuang,Seigo Ito,Bernard Wenger,Cedric Klein,Jacques-E Moser,Robin Humphry-Baker,Shaik M Zakeeruddin,Michael Grätzel. (2006-03-23) High molar extinction coefficient heteroleptic ruthenium complexes for thin film dye-sensitized solar cells.. Journal of the American Chemical Society, 128 ((12)): (4146-4154). [PMID:16551124] |
