Iron(III) chloride solution - 0.2 M in 2-methyltetrahydrofuran, high purity , CAS No.7705-08-0(2-MeTHF)

  • 0.2 M in 2-methyltetrahydrofuran
Item Number
I433833
Grouped product items
SKUSizeAvailabilityPrice Qty
I433833-50ml
50ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$289.90

Basic Description

SynonymsChlorure perrique [French] | Fe/ppm Pd for nitro group reductions | NSC 51150 | trichloroiron | EN300-19478 | EPA Pesticide Chemical Code 034901 | Fe(III) chloride | FT-0627302 | Iron(III) chloride, CP | Natural molysite | UNII-U38V3ZVV3V | AKOS015902743
Specifications & Purity0.2 M in 2-methyltetrahydrofuran
Storage TempStore at 2-8°C
Shipped InWet ice
Product Description

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. FeCl 3 is used in many biomass conversion processes because of its unique properties such as nontoxicity, low-cost, abundance, and high selectivity. Here, this product is 0.2 M in 2-methyltetrahydrofuran and thus aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks", and has been enhanced for catalytic efficiency. Click here for more information.


Application

Iron(III) chloride in greener solvent, 2-methyltetrahydrofuran (2-MeTHF) can be used: As a mild oxidant for phenolic coupling reaction. In dimerizing aryllithiumsand ketone enolates. As a mild Lewis acid catalyst to catalyzes ene reactions. In Nazarov cyclizations, Michael additions, and acetonation reactions. 2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

AI Insight

Names and Identifiers

IUPAC Name trichloroiron
INCHI InChI=1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
InChi Key RBTARNINKXHZNM-UHFFFAOYSA-K
Canonical SMILES Cl[Fe](Cl)Cl
Isomeric SMILES Cl[Fe](Cl)Cl
WGK Germany 3
PubChem CID 24380
UN Number 2924
Packing Group II
Molecular Weight 162.2

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS05,   GHS07,   GHS02
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

H318:Causes serious eye damage

H225:Highly Flammable liquid and vapor

H303:May be harmful if swallowed

H290:May be corrosive to metals

H401:Toxic to aquatic life

H371:May cause damage to organs

Precautionary Statements

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P405:Store locked up.

P501:Dispose of contents/container to ...

P233:Keep container tightly closed.

P240:Ground/bond container and receiving equipment.

P264:Wash hands [and …] thoroughly after handling.

P403+P235:Store in a well-ventilated place. Keep cool.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P270:Do not eat, drink or smoke when using this product.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P363:Wash contaminated clothing before reuse.

P308+P311:IF exposed or concerned: Call a POISON CENTER/doctor/...

P234:Keep only in original container.

P390:Absorb spillage to prevent material damage.

P242:Use only non-sparking tools.

P243:Take precautionary measures against static discharge.

P406:Store in corrosive resistant/... container with a resistant inner liner.

P301+P312+P330:IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth.

WGK Germany 3

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199. Deng Hao-Hua, Yang Hui-Jing, Huang Kai-Yuan, Zheng Yi-Jing, Xu Ying-Ying, Peng Hua-Ping, Liu Yin-Huan, Chen Wei, Hong Guo-Lin.  (2022)  Antenna effect of pyridoxal phosphate on the fluorescence of mitoxantrone-silicon nanoparticles and its application in alkaline phosphatase assay.  ANALYTICAL AND BIOANALYTICAL CHEMISTRY,  414  (17): (4877-4884).  [PMID:35576012] [10.1007/s00216-022-04110-7]
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203. Jinshu Huang, Yumei Jian, Hu Li, Zhen Fang.  (2022)  Lignin-derived layered 3D biochar with controllable acidity for enhanced catalytic upgrading of Jatropha oil to biodiesel.  CATALYSIS TODAY,  404  (35).  [PMID:] [10.1016/j.cattod.2022.04.016]
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206. Minkai Qin, Ruxue Fan, Jiadong Chen, Haiyan Wang, Xiaozhong Zheng, Shanjun Mao, Renfeng Du, Yong Wang.  (2022)  Elucidating electrocatalytic mechanism for large-scale cycloalkanol oxidation integrated with hydrogen evolution.  CHEMICAL ENGINEERING JOURNAL,  442  (136264).  [PMID:] [10.1016/j.cej.2022.136264]
207. Xiaolu Chen, Rongying Ma, Zhaoming Fu, Qianhong Su, Xingyu Luo, Yingchao Han, Yong Yang, Qingchun Deng.  (2022)  Metal-phenolic networks-encapsulated cascade amplification delivery nanoparticles overcoming cancer drug resistance via combined starvation/chemodynamic/chemo therapy.  CHEMICAL ENGINEERING JOURNAL,  442  (136221).  [PMID:] [10.1016/j.cej.2022.136221]
208. Ze Chen, Qi Yang, Donghong Wang, Ao Chen, Xinliang Li, Zhaodong Huang, Guojin Liang, Ying Wang, Chunyi Zhi.  (2022)  Tellurium: A High-Performance Cathode for Magnesium Ion Batteries Based on a Conversion Mechanism.  ACS Nano,  16  (4): (5349–5357).  [PMID:35357121] [10.1021/acsnano.1c07939]
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218. Jie Xu, Guangyong Zeng, Qingquan Lin, Yi Gu, Xuelian Wang, Zhenhua Feng, Arijit Sengupta.  (2022)  Application of 3D magnetic nanocomposites: MXene-supported Fe3O4@CS nanospheres for highly efficient adsorption and separation of dyes.  SCIENCE OF THE TOTAL ENVIRONMENT,  822  (153544).  [PMID:35104515] [10.1016/j.scitotenv.2022.153544]
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223. Devaraj Sabarinathan, Arumugam Selva Sharma, Akwasi Akomeah Agyekum, Marimuthu Murugavelu, Poorna Chandrika Sabapathy, Shujat Ali, Hamada Hassan, Huanhuan Li, Quansheng Chen.  (2022)  Thunnus albacares protein-mediated synthesis of water-soluble Copper nanoclusters as sensitive fluorescent probe for Ferric ion detection.  JOURNAL OF MOLECULAR STRUCTURE,  1254  (132333).  [PMID:] [10.1016/j.molstruc.2022.132333]
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Solution Calculators