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(Ethoxycarbonylmethyl)triphenylphosphonium chloride - technical, ≥90% (AT), high purity , CAS No.17577-28-5
Basic Description Synonyms 2-Ethoxy-2-oxoethyl)triphenylphosphonium chloride | Phosphonium, (2-ethoxy-2-oxoethyl)triphenyl-, chloride | 11BETA-PROSTAGLANDINF2ALPHA | Carbethoxymethyl triphenylphosphonium chloride | DJGHVEPNEJKZBF-UHFFFAOYSA-M | EINECS 241-548-2 | FT-0604874 | CS-01 Specifications & Purity technical grade, ≥90%(AT) Storage Temp Store at 2-8°C Shipped In Wet ice Grade technical grade Product Description Application
Reactant for: Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression Ring-opening reactions with Wittig reagents Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions Preparation of phosphonium derivatives of coumarin
Other Notes
Starting material for preparing the Wittig-reagent
Names and Identifiers IUPAC Name (2-ethoxy-2-oxoethyl)-triphenylphosphanium;chloride INCHI InChI=1S/C22H22O2P.ClH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1 InChi Key DJGHVEPNEJKZBF-UHFFFAOYSA-M Canonical SMILES CCOC(=O)C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-] Isomeric SMILES CCOC(=O)C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-] PubChem CID 87159 Molecular Weight 384.84
Certificates(CoA,COO,BSE/TSE and Analysis Chart) Safety and Hazards(GHS) Pictogram(s) GHS07 Signal Warning Hazard Statements H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: wash with plenty of water.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P362+P364: Take off contaminated clothing and wash it before reuse.
P264+P265: Wash hands [and …] thoroughly after handling. Do not touch eyes.
P337+P317: If eye irritation persists: Get medical help.
P332+P317: If skin irritation occurs: Get medical help.
P319: Get medical help if you feel unwell.
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