Copper(I) cyanide di(lithium chloride) complex solution - in anhydrous tetrahydrofuran, high purity

  • ~1M in anhydrous tetrahydrofuran
Item Number
C485962
Grouped product items
SKUSizeAvailabilityPrice Qty
C485962-10ml
10ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$221.90

Basic Description

Specifications & Purity~1M in anhydrous tetrahydrofuran
Storage TempRoom temperature,Argon charged
Shipped InNormal
Product Description

Description

Copper(I) cyanide di(lithium chloride) complex can be used for the synthesis of organocopper(I) reagents by transmetalation with organozinc and Grignard reagents. It is also a useful precursor to prepare organocuprate(I) reagents.

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Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Chemical and Physical Properties

SensitivityMoisture sensitive

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References

1. Tomas Hudlicky,Uwe Rinner,David Gonzalez,Hulya Akgun,Stefan Schilling,Peter Siengalewicz,Theodore A Martinot,George R Pettit.  (2002-12-07)  Total synthesis and biological evaluation of Amaryllidaceae alkaloids: narciclasine, ent-7-deoxypancratistatin, regioisomer of 7-deoxypancratistatin, 10b-epi-deoxypancratistatin, and truncated derivatives..  The Journal of organic chemistry,  67  ((25)): (8726-8743).  [PMID:12467383]
2. Tobias D Blümke, Fabian M Piller, Paul Knochel,.  (2010-04-10)  Preparation of highly functionalized alkylzinc halides from alkyl bromides using Mg, ZnCl2 and LiCl..  Chemical communications (Cambridge, England),  46  ((23)): ( 4082-4084 ).  [PMID:20379592]
3. Joel M Harris,Albert Padwa.  (2003-05-24)  A flexible approach toward trisubstituted piperidines and indolizidines: synthesis of 6-epi-indolizidine 223A..  The Journal of organic chemistry,  68  ((11)): (4371-4381).  [PMID:12762739]

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