Chloroform-d

  • ≥99.5%,≥99.96 atom% D
  • contains 0.03 % (v/v) TMS
Item Number
C776739
Grouped product items
SKUSizeAvailabilityPrice Qty
C776739-0.75ml
0.75ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$19.90
C776739-10×0.75ml
10×0.75ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$119.90
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Stable isotope (0)

Basic Description

Specifications & Purity≥99.5%,≥99.96 atom% D, contains 0.03 % (v/v) TMS
Storage TempStore at 2-8°C,Protected from light,Argon charged
Shipped InWet ice
Product Description

Chloroform-d (deuterochloroform, CDCl 3 ) is a deuterated NMR solvent containing 0.03% (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. It may be synthesized by reacting trichloroacetophenone and sodium deuteroxide. The influence of the number of pulses on its multiphoton decomposition (MPD) has been studied. Infrared spectral studies of C-D stretching and bending motions of CDCl 3 in different solvents have been investigated. The effect of chloroform-d on the interaction of water with activated carbons has been analyzed. The dependence of molecular reorientation of deuterated chloroform on pressure and temperature has been studied by Raman spectroscopy.

Application

Chloroform-d may be used in the synthesis of dichlorofluoromethane- d .

AI Insight

Names and Identifiers

IUPAC Name trichloro(deuterio)methane
INCHI InChI=1S/CHCl3/c2-1(3)4/h1H/i1D
InChi Key HEDRZPFGACZZDS-MICDWDOJSA-N
Canonical SMILES C(Cl)(Cl)Cl
Isomeric SMILES [2H]C(Cl)(Cl)Cl
WGK Germany 3
Alternate CAS 67-66-3(unlabelled)
PubChem CID 71583
UN Number 1888
Packing Group III
Molecular Weight 120.38
Beilstein 1697633

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS08
Signal Danger
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H331:Toxic if inhaled

H351:Suspected of causing cancer

H373:Causes damage to organs through prolonged or repeated exposure

H302:Harmful if swallowed

H336:May cause drowsiness or dizziness

H372:Causes damage to organs through prolonged or repeated exposure

H361:Suspected of damaging fertility or the unborn child

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P203:Obtain, read and follow all safety instructions before use.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P317:IF SWALLOWED: Get medical help.

P318:if exposed or concerned, get medical advice.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P316:Get emergency medical help immediately.

P319:Get medical help if you feel unwell.

WGK Germany 3
Class 6.1

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