Bis(triphenylsilyl) chromate - 96%, high purity , CAS No.1624-02-8

  • ≥96%
Item Number
B468090
Grouped product items
SKUSizeAvailabilityPrice Qty
B468090-1g
1g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$184.90
B468090-10g
10g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$1,018.90

Basic Description

Synonymschromium(2+);oxido(triphenyl)silane;dihydrate | FT-0697782 | MFCD01736354 | Bis(triphenylsilyl) chromate | Bis(triphenylsilyl)chromate 96 | bis(triphenylsilyl)chromate 96
Specifications & Purity≥96%
Product Description

Description

Reactant for the XPS and XRD characterization of chromium-silica catalystsSilyl chromate catalyst forOlefin polymerization and ethylene polymerizationBenzylic oxidations used as a phase transfer catalystBis(triphenylsilyl) chromate [(Ph3SiO)2] can be used as a catalyst:For ethylene polymerization.For the conversion of secondary benzylic and allylic trimethylsilyl ethers to ketones by oxidation reaction usingtert-butyl hydroperoxide.It can also be used to prepare supported catalysts with silica gel or montmorillonite K-10. These catalysts can be used in the oxidation of alcohols to corresponding carbonyl compounds.

AI Insight

Names and Identifiers

IUPAC Name chromium(2+);oxido(triphenyl)silane;dihydrate
INCHI InChI=1S/2C18H15OSi.Cr.2H2O/c2*19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;;2*1H2/q2*-1;+2;;
InChi Key VYQXSBLHPWPXGL-UHFFFAOYSA-N
Canonical SMILES C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)[O-].C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)[O-].O.O.[Cr+2]
Isomeric SMILES C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)[O-].C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)[O-].O.O.[Cr+2]
WGK Germany 2
RTECS GB2685000
PubChem CID 102059955
Molecular Weight 634.79

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS08,   GHS09,   GHS07
Signal Danger
Hazard Statements

H311:Toxic in contact with skin

H317:May cause an allergic skin reaction

H400:Very toxic to aquatic life

H410:Very toxic to aquatic life with long lasting effects

H350:May cause cancer

H361:Suspected of damaging fertility or the unborn child

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P272:Contaminated work clothing should not be allowed out of the workplace.

P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P391:Collect spillage.

P361+P364:Take off immediately all contaminated clothing and wash it before reuse.

P203:Obtain, read and follow all safety instructions before use.

P318:if exposed or concerned, get medical advice.

P316:Get emergency medical help immediately.

WGK Germany 2
RTECS GB2685000
RIDADR UN2811-class6.1-PG3-EHS-RQ-Toxicsolids,organic,n.o.s.HI:all

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