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Bis(triphenylsilyl) chromate - 96%, high purity , CAS No.1624-02-8
Basic Description Synonyms chromium(2+);oxido(triphenyl)silane;dihydrate | FT-0697782 | MFCD01736354 | Bis(triphenylsilyl) chromate | Bis(triphenylsilyl)chromate 96 | bis(triphenylsilyl)chromate 96 Specifications & Purity ≥96% Product Description Description
Reactant for the XPS and XRD characterization of chromium-silica catalystsSilyl chromate catalyst forOlefin polymerization and ethylene polymerizationBenzylic oxidations used as a phase transfer catalystBis(triphenylsilyl) chromate [(Ph3SiO)2] can be used as a catalyst:For ethylene polymerization.For the conversion of secondary benzylic and allylic trimethylsilyl ethers to ketones by oxidation reaction usingtert-butyl hydroperoxide.It can also be used to prepare supported catalysts with silica gel or montmorillonite K-10. These catalysts can be used in the oxidation of alcohols to corresponding carbonyl compounds.
Names and Identifiers IUPAC Name chromium(2+);oxido(triphenyl)silane;dihydrate INCHI InChI=1S/2C18H15OSi.Cr.2H2O/c2*19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;;2*1H2/q2*-1;+2;; InChi Key VYQXSBLHPWPXGL-UHFFFAOYSA-N Canonical SMILES C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)[O-].C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)[O-].O.O.[Cr+2] Isomeric SMILES C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)[O-].C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)[O-].O.O.[Cr+2] WGK Germany 2 RTECS GB2685000 PubChem CID 102059955 Molecular Weight 634.79
Certificates(CoA,COO,BSE/TSE and Analysis Chart) Safety and Hazards(GHS) Pictogram(s) GHS06 , GHS08 , GHS09 , GHS07 Signal Danger Hazard Statements H311: Toxic in contact with skin
H317: May cause an allergic skin reaction
H400: Very toxic to aquatic life
H410: Very toxic to aquatic life with long lasting effects
H350: May cause cancer
H361: Suspected of damaging fertility or the unborn child
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: wash with plenty of water.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P272: Contaminated work clothing should not be allowed out of the workplace.
P333+P313: IF SKIN irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
P361+P364: Take off immediately all contaminated clothing and wash it before reuse.
P203: Obtain, read and follow all safety instructions before use.
P318: if exposed or concerned, get medical advice.
P316: Get emergency medical help immediately.
WGK Germany 2 RTECS GB2685000 RIDADR UN2811-class6.1-PG3-EHS-RQ-Toxicsolids,organic,n.o.s.HI:all
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