Acrolein dimethyl acetal undergoes cationic α-diimine palladium chelate catalyzed copolymerization with ethene to yield branched copolymers.
application:
Acrolein dimethyl acetal was used in the facile one step synthesis of 4-hydroxy-2E-nonenal and its dimethyl acetal via a cross-metathesis reaction with octen-3-ol.
1.Weidong Li, Xiaochun Zhang, Auke Meetsma, Bart Hessen,. (2004-09-30) Palladium-catalyzed copolymerization of ethene with acrolein dimethyl acetal: catalyst action and deactivation.. Journal of the American Chemical Society, 126 ((39)):( 12246-12247 ). [PMID:15453740]
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