2,3,5,6-Tetrafluoro-7,7',8,8'-tetracyanoquinodimethane - 97%, high purity , CAS No.29261-33-4

  • ≥97%
Item Number
T101365
Grouped product items
SKUSizeAvailabilityPrice Qty
T101365-25mg
25mg
5
$62.90
T101365-100mg
100mg
2
$191.90
T101365-500mg
500mg
4
$863.90
T101365-1g
1g
3
$1,090.90
T101365-5g
5g
2
$4,907.90

Basic Description

SynonymsMFCD00042382 | BCP18920 | 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-quinodimethane | YSWG343 | (2,3,5,6-Tetrafluoro-2,5-cyclohexadiene-1,4-diylidene)dimalononitrile | F4TCNQ | 2-[4-(dicyanomethylene)-2,3,5,6-tetrafluoro-cyclohexa-2,5-dien-1-ylidene]propanedi
Specifications & Purity≥97%
Shipped InNormal
Product Description

2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ) is a dopant used in the fabrication of organic semiconductors. It can tune the electronic properties as its lowest unoccupied molecular orbital is at a desirable energy level required to oxidize a wide range of semiconductors.
2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ) are p-type molecules, used as a strong acceptor dopant , it generates free holes.

Application:

F4-TCNQ can be doped with poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) to form a hole transport material (HTL), which can be used to achieve an energy efficiency of 16% for a semi-transparent perovskite solar cell.It can be used as a p-type dopant to form a blended composite film with poly(3-hexylthiophene) (P3HT) having enhanced charge mobility, which can be potentially useful in organic photovoltaics.
F4-TCNQ is the p-type dopant for hole-only devices and field effect transistors with organic hole transport layers (HTL).It is used in the preparation of a bilayer structure of F4-TCNQ and pentacene to study improved thermoelectric performance of organic thin films.

AI Insight

Names and Identifiers

Pubchem Sid488192385
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488192385
IUPAC Name 2-[4-(dicyanomethylidene)-2,3,5,6-tetrafluorocyclohexa-2,5-dien-1-ylidene]propanedinitrile
INCHI InChI=1S/C12F4N4/c13-9-7(5(1-17)2-18)10(14)12(16)8(11(9)15)6(3-19)4-20
InChi Key IXHWGNYCZPISET-UHFFFAOYSA-N
Canonical SMILES C(#N)C(=C1C(=C(C(=C(C#N)C#N)C(=C1F)F)F)F)C#N
Isomeric SMILES C(#N)C(=C1C(=C(C(=C(C#N)C#N)C(=C1F)F)F)F)C#N
WGK Germany 3
PubChem CID 2733307
Molecular Weight 276.15
Beilstein 2157887
Reaxy-Rn 2157887

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

13 results found

Lot NumberCertificate TypeDateItem
C2504558Certificate of AnalysisMar 07, 2025 T101365
C2504565Certificate of AnalysisMar 07, 2025 T101365
C2504573Certificate of AnalysisMar 07, 2025 T101365
C2504625Certificate of AnalysisMar 07, 2025 T101365
C2504637Certificate of AnalysisMar 07, 2025 T101365
C2528124Certificate of AnalysisMar 07, 2025 T101365
B2426207Certificate of AnalysisNov 24, 2022 T101365
G2325051Certificate of AnalysisNov 24, 2022 T101365
K2212401Certificate of AnalysisNov 24, 2022 T101365
K2212403Certificate of AnalysisNov 24, 2022 T101365
K2212455Certificate of AnalysisNov 24, 2022 T101365
K2212580Certificate of AnalysisNov 24, 2022 T101365
K2308188Certificate of AnalysisNov 24, 2022 T101365

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Safety and Hazards(GHS)

Pictogram(s) GHS06
Signal Danger
Hazard Statements

H301:Toxic if swallowed

H311:Toxic in contact with skin

H331:Toxic if inhaled

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P330:Rinse mouth.

P361+P364:Take off immediately all contaminated clothing and wash it before reuse.

P301+P316:IF SWALLOWED: Get emergency medical help immediately.

P316:Get emergency medical help immediately.

WGK Germany 3
Reaxy-Rn 2157887

Related Documents

Reviews

Customer Reviews

Citations of This Product

1. Junsheng Luo, Chunyang Jia, Zhongquan Wan, Fei Han, Bowen Zhao, Ruilin Wang.  (2017)  The novel dopant for hole-transporting material opens a new processing route to efficiently reduce hysteresis and improve stability of planar perovskite solar cells.  JOURNAL OF POWER SOURCES,  342  (886).  [PMID:] [10.1016/j.jpowsour.2017.01.010]

References

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11. Jack Fuzell,Ian E Jacobs,Sophia Ackling,Thomas F Harrelson,David M Huang,Delmar Larsen,Adam J Moulé.  (2016-11-04)  Optical Dedoping Mechanism for P3HT:F4TCNQ Mixtures..  The journal of physical chemistry letters,  ((21)): (4297-4303).  [PMID:27731993]
12. Shrawan Roy,Wooseon Choi,Sera Jeon,Do-Hwan Kim,Hyun Kim,Seok Joon Yun,Yongjun Lee,Jaekwang Lee,Young-Min Kim,Jeongyong Kim.  (2018-06-21)  Atomic Observation of Filling Vacancies in Monolayer Transition Metal Sulfides by Chemically Sourced Sulfur Atoms..  Nano letters,  18  ((7)): (4523-4530).  [PMID:29921125]
13. Hans He,Kyung Ho Kim,Andrey Danilov,Domenico Montemurro,Liyang Yu,Yung Woo Park,Floriana Lombardi,Thilo Bauch,Kasper Moth-Poulsen,Tihomir Iakimov,Rositsa Yakimova,Per Malmberg,Christian Müller,Sergey Kubatkin,Samuel Lara-Avila.  (2018-09-29)  Uniform doping of graphene close to the Dirac point by polymer-assisted assembly of molecular dopants..  Nature communications,  ((1)): (3956-3956).  [PMID:30262825]
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18. Junsheng Luo, Chunyang Jia, Zhongquan Wan, Fei Han, Bowen Zhao, Ruilin Wang.  (2017)  The novel dopant for hole-transporting material opens a new processing route to efficiently reduce hysteresis and improve stability of planar perovskite solar cells.  JOURNAL OF POWER SOURCES,  342  (886).  [PMID:] [10.1016/j.jpowsour.2017.01.010]

Solution Calculators