[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) - Pd 18.5%, high purity , CAS No.19978-61-1

  • Pd 18.5%
Item Number
D111325
Grouped product items
SKUSizeAvailabilityPrice Qty
D111325-1g
1g
3
$62.90
D111325-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$187.90
D111325-10g
10g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$336.90

Basic Description

SynonymsUmicore CX91 | PdCl2(dppe) | AKOS015964009 | DTXSID00454105 | 1,2-Bis(diphenylphosphino)ethane palladium(II)dichloride | PdCl2(dppe) | SCHEMBL376175 | [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), 98% | Dichloro(1,2-bis(diphenylphosphino)ethane
Specifications & PurityPd 18.5%
Legal InformationProduct of Umicore
Storage TempArgon charged
Shipped InNormal
Product Description

Product class

M-P, Homogeneous Catalysts, Bidentate Ligands, Phosphorus Ligands - Achiral


Chemical properties

Chemical formula

C26H24Cl2P2Pd

Empirical formula

[Pd(dppe)Cl2]

Molecular weight

575.75

Metal

Pd

Theoretical metal content

18

Physical state

powder

Color

white

Applications & references

Palladium catalyzed intermolecular decarboxylative coupling in the presence of reactive C-H groups.


Reference: J. Org. Chem. 2010, 75, 1550. (DOI: 10.1021/jo9022793)

AI Insight

Names and Identifiers

Pubchem Sid504765963
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/504765963
IUPAC Name dichloropalladium;2-diphenylphosphanylethyl(diphenyl)phosphane
INCHI InChI=1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChi Key LDJXFZUGZASGIW-UHFFFAOYSA-L
Canonical SMILES C1=CC=C(C=C1)P(CCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Pd]Cl
Isomeric SMILES C1=CC=C(C=C1)P(CCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Pd]Cl
WGK Germany 3
PubChem CID 11071931
Molecular Weight 575.74
Reaxy-Rn 14861078

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

1 results found

Lot NumberCertificate TypeDateItem
G1514012Certificate of AnalysisJan 05, 2023 D111325

Safety and Hazards(GHS)

Pictogram(s) GHS05,   GHS07
Signal Danger
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H413:May cause long lasting harmful effects to aquatic life

H302:Harmful if swallowed

H318:Causes serious eye damage

H317:May cause an allergic skin reaction

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P272:Contaminated work clothing should not be allowed out of the workplace.

P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P317:IF SWALLOWED: Get medical help.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P317:Get emergency medical help.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3
Reaxy-Rn 14861078

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References

1. Leila Tabrizi, Hossein Chiniforoshan,.  (2017-10-07)  The cytotoxicity and mechanism of action of new multinuclear Scaffold Au.  Dalton transactions (Cambridge, England : 2003),  46  ((41)): ( 14164-14173 ).  [PMID:28984321]

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